Sign of excited spin state magnetic anisotropy parameters

By using high frequency high field EPR spectroscopy we demonstrate how to extract the sign of magnetic anisotropy parameters pertinent to excited spin multiplets of antiferromagnetically coupled clusters. The method is demonstrated on a manganese(II) dimer.

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Bibliographic Details
Published in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2006-03, Vol.63 (3), p.541-543
Main Authors: Huang, Ping, Anderlund, Magnus, Weihe, Høgni, Barra, Anne-Laure, Sun, Licheng
Format: Article
Language:English
Subjects:
Anisotropy
Chemical Phenomena
Chemistry
Dimerization
Electron Spin Resonance Spectroscopy - methods
epr
EPR spectroscopy
Excited spin state parameters
Iron - chemistry
Magnetics
Manganese - chemistry
Manganese Compounds - chemistry
Models, Statistical
Spin Labels
Citations: Items that this one cites
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Description
Summary:By using high frequency high field EPR spectroscopy we demonstrate how to extract the sign of magnetic anisotropy parameters pertinent to excited spin multiplets of antiferromagnetically coupled clusters. The method is demonstrated on a manganese(II) dimer.
ISSN:1386-1425
1873-3557
DOI:10.1016/j.saa.2005.05.042