Iron hydrogenase active site mimic holding a proton and a hydride

The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the title species was characterized by IR and NMR spectroscopy and is reduced at more positive potential than any other mimic of this kind.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2006-02, Vol.5 (5), p.520-522
Main Authors: Schwartz, Lennart, Eilers, Gerriet, Eriksson, Lars, Gogoll, Adolf, Lomoth, Reiner, Ott, Sascha
Format: Article
Language:English
Subjects:
Binding Sites
Chemistry
Hydrogen - chemistry
Hydrogenase - chemistry
Hydrogenase - metabolism
Iron-Sulfur Proteins - chemistry
Iron-Sulfur Proteins - metabolism
Kemi
Magnetic Resonance Spectroscopy
Models, Molecular
Molecular Mimicry
NATURAL SCIENCES
NATURVETENSKAP
Protons
Spectrophotometry, Infrared
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Description
Summary:The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the title species was characterized by IR and NMR spectroscopy and is reduced at more positive potential than any other mimic of this kind.
ISSN:1359-7345
1364-548X
DOI:10.1039/b514280f