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Magic numbers and stabilities of heavy water clusters, (D2O)ND+, N = 3 −48
[Display omitted] •Determines the stabilities of heavy water clusters.•Slightly smaller magicity of the N = 21 cluster compared to normal water.•No difference observed for N = 28: The difference ascribed to the special geometric structure of the N = 21 cluster. The abundance spectrum of deuterated h...
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| Published in: | International journal of mass spectrometry 2019-06, Vol.440, p.14-19 |
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| Language: | English |
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| container_end_page | 19 |
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| container_start_page | 14 |
| container_title | International journal of mass spectrometry |
| container_volume | 440 |
| creator | Hansen, K. Ryding, M.J. Uggerud, E. |
| description | [Display omitted]
•Determines the stabilities of heavy water clusters.•Slightly smaller magicity of the N = 21 cluster compared to normal water.•No difference observed for N = 28: The difference ascribed to the special geometric structure of the N = 21 cluster.
The abundance spectrum of deuterated heavy water clusters has been measured, and relative dissociation energies were extracted from the abundances. The dissociation energies are similar to those of protonated light water clusters, except for a slightly reduced excess stability of the N = 21 cluster relative to the N = 22 cluster. The difference is interpreted in terms of the special geometry of the N = 21 cluster. The absence of a similar effect for N = 28/29 suggests that the stability of the N = 28 cluster is not due to a closed shell structure. |
| doi_str_mv | 10.1016/j.ijms.2019.03.003 |
| format | article |
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•Determines the stabilities of heavy water clusters.•Slightly smaller magicity of the N = 21 cluster compared to normal water.•No difference observed for N = 28: The difference ascribed to the special geometric structure of the N = 21 cluster.
The abundance spectrum of deuterated heavy water clusters has been measured, and relative dissociation energies were extracted from the abundances. The dissociation energies are similar to those of protonated light water clusters, except for a slightly reduced excess stability of the N = 21 cluster relative to the N = 22 cluster. The difference is interpreted in terms of the special geometry of the N = 21 cluster. The absence of a similar effect for N = 28/29 suggests that the stability of the N = 28 cluster is not due to a closed shell structure.</description><identifier>ISSN: 1387-3806</identifier><identifier>EISSN: 1873-2798</identifier><identifier>DOI: 10.1016/j.ijms.2019.03.003</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Atom and Molecular Physics and Optics ; Atom- och molekylfysik och optik ; Binding energies ; Clusters ; Fysikalisk kemi ; Heavy water ; Physical Chemistry ; Unimolecular reactions</subject><ispartof>International journal of mass spectrometry, 2019-06, Vol.440, p.14-19</ispartof><rights>2019 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27903,27904</link.rule.ids><backlink>$$Uhttps://gup.ub.gu.se/publication/278490$$DView record from Swedish Publication Index$$Hfree_for_read</backlink></links><search><creatorcontrib>Hansen, K.</creatorcontrib><creatorcontrib>Ryding, M.J.</creatorcontrib><creatorcontrib>Uggerud, E.</creatorcontrib><title>Magic numbers and stabilities of heavy water clusters, (D2O)ND+, N = 3 −48</title><title>International journal of mass spectrometry</title><description>[Display omitted]
•Determines the stabilities of heavy water clusters.•Slightly smaller magicity of the N = 21 cluster compared to normal water.•No difference observed for N = 28: The difference ascribed to the special geometric structure of the N = 21 cluster.
The abundance spectrum of deuterated heavy water clusters has been measured, and relative dissociation energies were extracted from the abundances. The dissociation energies are similar to those of protonated light water clusters, except for a slightly reduced excess stability of the N = 21 cluster relative to the N = 22 cluster. The difference is interpreted in terms of the special geometry of the N = 21 cluster. The absence of a similar effect for N = 28/29 suggests that the stability of the N = 28 cluster is not due to a closed shell structure.</description><subject>Atom and Molecular Physics and Optics</subject><subject>Atom- och molekylfysik och optik</subject><subject>Binding energies</subject><subject>Clusters</subject><subject>Fysikalisk kemi</subject><subject>Heavy water</subject><subject>Physical Chemistry</subject><subject>Unimolecular reactions</subject><issn>1387-3806</issn><issn>1873-2798</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNotkM1KAzEUhYMoWKsv4CpLxc54kzvNJKALaf2D2oLoOiQzmZqhf0xmWrpz6doX8Z36JE7RxeEcLofL4SPknEHMgInrMvblPMQcmIoBYwA8IB0mU4x4quRhm1GmEUoQx-QkhBIAUuyLDnl9MVOf0UUzt64K1CxyGmpj_czX3gW6LOiHM-st3ZjaVTSbNaH10KMXQz65HA-venS8-_y5bYWtdl_fiTwlR4WZBXf2713y_nD_NniKRpPH58HdKHI8EXVkWa4E2IRzlSrOlOUpFogGc4vcYcFMAQKUsyhlXyRMYMKSPkCeG2YkWuyS6O9v2LhVY_Wq8nNTbfXSeD1tVro9TRsdnOapTBS0_Zu_vmtHrb2rdMi8W2Qu95XLap0vvWag9zx1qfc89Z6nBtQtT_wF81dshA</recordid><startdate>20190601</startdate><enddate>20190601</enddate><creator>Hansen, K.</creator><creator>Ryding, M.J.</creator><creator>Uggerud, E.</creator><general>Elsevier B.V</general><scope>ADTPV</scope><scope>AOWAS</scope><scope>F1U</scope></search><sort><creationdate>20190601</creationdate><title>Magic numbers and stabilities of heavy water clusters, (D2O)ND+, N = 3 −48</title><author>Hansen, K. ; Ryding, M.J. ; Uggerud, E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e246t-b1d960b422979219b273f33a3db32e3f1af0609eb388564163414500dda1a83b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Atom and Molecular Physics and Optics</topic><topic>Atom- och molekylfysik och optik</topic><topic>Binding energies</topic><topic>Clusters</topic><topic>Fysikalisk kemi</topic><topic>Heavy water</topic><topic>Physical Chemistry</topic><topic>Unimolecular reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hansen, K.</creatorcontrib><creatorcontrib>Ryding, M.J.</creatorcontrib><creatorcontrib>Uggerud, E.</creatorcontrib><collection>SwePub</collection><collection>SwePub Articles</collection><collection>SWEPUB Göteborgs universitet</collection><jtitle>International journal of mass spectrometry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hansen, K.</au><au>Ryding, M.J.</au><au>Uggerud, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magic numbers and stabilities of heavy water clusters, (D2O)ND+, N = 3 −48</atitle><jtitle>International journal of mass spectrometry</jtitle><date>2019-06-01</date><risdate>2019</risdate><volume>440</volume><spage>14</spage><epage>19</epage><pages>14-19</pages><issn>1387-3806</issn><eissn>1873-2798</eissn><abstract>[Display omitted]
•Determines the stabilities of heavy water clusters.•Slightly smaller magicity of the N = 21 cluster compared to normal water.•No difference observed for N = 28: The difference ascribed to the special geometric structure of the N = 21 cluster.
The abundance spectrum of deuterated heavy water clusters has been measured, and relative dissociation energies were extracted from the abundances. The dissociation energies are similar to those of protonated light water clusters, except for a slightly reduced excess stability of the N = 21 cluster relative to the N = 22 cluster. The difference is interpreted in terms of the special geometry of the N = 21 cluster. The absence of a similar effect for N = 28/29 suggests that the stability of the N = 28 cluster is not due to a closed shell structure.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.ijms.2019.03.003</doi><tpages>6</tpages></addata></record> |
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| ispartof | International journal of mass spectrometry, 2019-06, Vol.440, p.14-19 |
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| language | eng |
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| source | ScienceDirect Freedom Collection |
| subjects | Atom and Molecular Physics and Optics Atom- och molekylfysik och optik Binding energies Clusters Fysikalisk kemi Heavy water Physical Chemistry Unimolecular reactions |
| title | Magic numbers and stabilities of heavy water clusters, (D2O)ND+, N = 3 −48 |
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