Nano structured diatom frustules incorporated into TiO2 photoelectrodes to enhance performance of quasi-solid-state dye-sensitized solar cells

• Published in: Optical materials 2023-12, Vol.146, p.114514, Article 114514
• Main Authors: T.M.W.J., Bandara, Withanage, S.S., Wijayaratne, K.B., Dissanayake, M.A.K.L., Bandara, K.M.S.P., Mellander, B.-E., Furlani, M., Albinsson, I.
• Format: Article
• Language: English
• Subjects: Atom and Molecular Physics and Optics; Atom- och molekylfysik och optik; Diatom frustules; Dye-sensitized solar cells; Efficiency enhancement; Gel electrolytes; Multilayers photoelectrodes; TiO2
• ISSN: 0925-3467; 1873-1252
• DOI: 10.1016/j.optmat.2023.114514

Diatom frustules are incorporated into multilayer photoelectrodes intending to enhance efficiency in dye-sensitized solar cells utilizing their light interaction properties. A specific, but ubiquitous in all oceans, pennate-type diatom frustules were used to form the composite layers. Single, double, and triple-layer photoelectrodes were constructed with pure TiO2 (control measurements) as well as with a TiO2/diatom frustule composite. The electrodes were prepared using TiO2 nanoparticles of two sizes (13 and 21 nm) and were analyzed using UV visible absorption and XRD spectra. The morphology of frustules and electrodes were analyzed using scanning electron microscopy. The performance for each photoanode configuration was measured by assembling photoelectrochemical solar cells fabricated with a Pt counter electrode and a gel polymer electrolyte that excludes volatile solvents. The efficiency of the control cell is 3.37%. After replacing the topmost TiO2 layer with a TiO2/diatom frustule composite layer, efficiency increases to 6.78%. This is an impressive efficiency enhancement of 101%. The short circuit current density of frustule-incorporated three-layer cells is 18.1 mA cm−1 while for the control cell it is 8.98 mA cm−1. The enhanced efficiency of cells made with TiO2/diatom frustule composite electrodes and a polyethylene oxide-based gel polymer electrolyte can be attributed to the improved light absorption by the photoanode due to optical scattering and light-trapping effects caused by the presence of diatom frustules. Frustules also can assist in enhancing dye adsorption by increasing the effective specific surface area of the composite photoelectrode due to their nanoporous structure. [Display omitted] •Diatom frustules are infused into TiO2 multilayer photoanodes to enhance DSSC efficiency.•Photoelectrodes with up to 3 layers of TiO2/diatom frustule were constructed.•101% efficiency boost is noted when frustules are impregnated to the topmost TiO2 layer.•Cells showed good short-term stability due to the use of apt gel polymer electrolyte.•Nanostructures of biological origin can be utilized to harness solar energy efficiently.