Facile strategies for synthesis of functionalized mesoporous silicas for the removal of rare-earth elements and heavy metals from aqueous systems

• Published in: Microporous and mesoporous materials 2021-02, Vol.315, p.110919, Article 110919
• Main Authors: Dudarko, О., Kobylinska, N., Mishra, B., Kessler, V.G., Tripathi, Bijay P., Seisenbaeva, G.A.
• Format: Article
• Language: English
• Subjects: Adsorption; Heavy metal ions; Materialkemi; Materials Chemistry; Ordered mesoporous silica; Recovery; Water purification
• ISSN: 1387-1811; 1873-3093; 1873-3093
• DOI: 10.1016/j.micromeso.2021.110919

A series of adsorbents of SBA-15-type with ethylenediaminetriacetic (EDTA), phosphonic, and ammonium groups as ligands were synthesized using the template method based on sodium metasilicate as the major starting reagent. The detailed characterizations using SEM, TEM, XRD, and N2 sorption/desorption measurements of synthesized sorbents confirmed an ordered mesoporous structures with uniform pore diameter and large surface area. Regardless of the functional groups concentration, the synthesized sorbents showed significantly higher adsorption capacities for target ions than neat SBA-15. The observed adsorption mechanisms were predominantly based on complexation and electrostatic interactions between metal ions and various functional groups present on the adsorbent surfaces. The synthesized SBA-15 derivatives were used for removal of different metal ions such as Fe(III), Ni(II), Cu(II), Pb(II), Nd(III), and Dy(III) from water (pH ≥ 1). The highest adsorption capacity was obtained for the bifunctional (-EDTA/phosphonic groups) modified adsorbent, reaching up to 119.05 mg g−1 for Fe(III), 246.95 mg g−1 for Pb(II), 246.95 mg g−1 for Cu(II), 238.10 mg g−1 for Nd(III) and 243.90 mg g−1 for Dy(III). The adsorption data were successfully fitted to the Langmuir and Freundlich models, revealing a monolayer chemisorption of REEs on the mesoporous samples. Metal desorption and adsorbent recycling were also found to be efficient under acidic condition (0.5–1.0 M). These properties highlight the perspective uses of functionalized mesoporous silicas for the rapid and potentially selective removal of REEs and heavy metal ions from the complex water samples and technological mixtures. [Display omitted] •Mono- and bifunctional SBA-15 type silica were synthesized using the one-step template approach.•The adsorption performance was optimized by the combination of different functional groups.•The metal ions uptake was achieved by coupling of an access and complexation mechanism.•The capacity and selectivity of the materials were tested for individual and multi-element solutions.•The samples demonstrated very high uptake capacity (240 mg of REE3+g-1) and selectivity toward REEs.