A Remarkable Cycloaddition of Bis(arylsulfonyl)iodonium Ylide with Norbornene Derivatives for the Direct Synthesis of Functionalized Indanes

Abstract The reaction of bis(arylsulfonyl)iodonium ylides with a variety of norbornene derivatives 3 affords functionalized indanes 4 in good yields through an unusual cycloaddition. This diastereoselective cycloaddition provides a convenient preparative route to multicyclic structures of well defin...

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Bibliographic Details
Published in:Synlett 2003-07, Vol.2003 (8)
Main Authors: Adam, Waldemar, Gogonas, Efstathios P., Hadjiarapoglou, Lazaros P.
Format: Article
Language:English
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Summary:Abstract The reaction of bis(arylsulfonyl)iodonium ylides with a variety of norbornene derivatives 3 affords functionalized indanes 4 in good yields through an unusual cycloaddition. This diastereoselective cycloaddition provides a convenient preparative route to multicyclic structures of well defined stereochemical configuration.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2003-39894