Use of ionic liquid in leaching process of brass wastes for copper and zinc recovery

• Published in: International journal of minerals, metallurgy and materials metallurgy and materials, 2014-02, Vol.21 (2), p.138-143
• Main Authors: Kilicarslan, Ayfer, Saridede, Muhlis Nezihi, Stopic, Srecko, Friedrich, Bernd
• Format: Article
• Language: English
• Subjects: Aqueous solutions; Ashes; Brasses; Ceramics; Characterization and Evaluation of Materials; Chemistry and Materials Science; Composites; Copper; Corrosion and Coatings; DISSOLUTION; Glass; Hydrogen peroxide; Ionic liquids; Leaching; Materials Science; Metallic Materials; Natural Materials; Oxidants; Oxidizing agents; POLLUTION; Pressure; Reagents; Surfaces and Interfaces; Thin Films; Tribology; Zinc; 回收; 废料; 浸出过程; 溶解时间; 离子液体; 过硫酸氢钾; 锌; 黄铜
• ISSN: 1674-4799; 1869-103X
• DOI: 10.1007/s12613-014-0876-y

Brass ash from the industrial brass manufacturer in Turkey was leached using the solutions of ionic liquid （IL） 1-butyl-3-methyl-imi-dazolium hydrogen sulfate （[bmim]HSO4） at ambient pressure in the presence of hydrogen peroxide （H2O2） and potassium peroxymonosulfate （oxone） as the oxidants. Parameters affecting leaching efficiency, such as dissolution time, IL concentration, and oxidizing agent addition, were investigated. The results show that [bmim]HSO4 is an efficient IL for the brass ash leaching, providing the dissolution efficiencies of 99%for Zn and 24.82%for Cu at a concentration of 50vol%[bmim]HSO4 in the aqueous solution without any oxidant. However, more than 99%of zinc and 82%of copper are leached by the addition of 50vol%H2O2 to the [bmim]HSO4 solution. Nevertheless, the oxone does not show the promising oxidant behavior in leaching using [bmim]HSO4.