Oxidation behavior of artificial magnetite pellets

• Published in: International journal of minerals, metallurgy and materials metallurgy and materials, 2017-06, Vol.24 (6), p.603-610
• Main Authors: Zhang, Han-quan, Fu, Jin-tao
• Format: Article
• Language: English
• Subjects: Activation energy; Ceramics; Characterization and Evaluation of Materials; Chemical reactions; Chemistry and Materials Science; Composites; Corrosion and Coatings; Diameters; Glass; Iron compounds; Magnetite; Materials Science; Metallic Materials; Minerals; Natural Materials; Oxidation; Oxidation process; Oxygen; Pellets; Physical properties; Reaction mechanisms; Surfaces and Interfaces; Temperature; Thin Films; Tribology
• ISSN: 1674-4799; 1869-103X
• DOI: 10.1007/s12613-017-1442-1

The oxidation behavior of artificial magnetite pellets was investigated through measurements of the oxidation degree and mineralogical analysis. The results show that artificial magnetite pellets are much easier to oxidize than natural magnetite. The oxidation is controlled through two different reaction mechanisms. The oxidation of artificial magnetite is dominated by internal diffusion, with an activation energy of 8.40 kJ/mol, at temperatures less than 800°C, whereas it is controlled by chemical reaction, with a reaction activation energy of 67.79 kJ/mol, at temperatures greater than 800°C. In addition, factors such as the oxygen volume fraction and the pellet diameter strongly influence the oxidation of artificial magnetite: a larger oxygen volume fraction and a smaller pellet diameter result in a much faster oxidation process.