Conceptual carbon-reduction process design and quantitative sustainable assessment for concentrating high purity ethylene from wasted refinery gas

• Published in: Chinese journal of chemical engineering 2023-05, Vol.57 (5), p.290-308
• Main Authors: Liu, Jixiang, Zhou, Xin, Yang, Gengfei, Zhao, Hui, Zhang, Zhibo, Feng, Xiang, Yan, Hao, Liu, Yibin, Chen, Xiaobo, Yang, Chaohe
• Format: Article
• Language: English
• Subjects: Carbon-reduction; Computer simulation; Life cycle environment assessment; Optimal design; Wasted treatment
• ISSN: 1004-9541; 2210-321X
• DOI: 10.1016/j.cjche.2022.09.020

We developed a conceptual design process model of the polymer-grade ethylene recovery process (SCOAS) from waste refinery gas using the oil absorption method. Based on the novel approach, heat pump-assisted thermal integration (HPSCOAS) is used to optimize and compare the traditional process. The results show that the novel processes show excellent technical, economic, and environmental performance. [Display omitted] The direct emission of waste refinery gas after combustion will cause a severe greenhouse effect. Recovering high-value-added ethylene from wasted refinery gas has fundamental economic and environmental significance. Due to the complexity of the composition of refinery waste gas, designing and optimizing the whole recovery process is still a challenging task. Herein, a novel process (SCOAS) was proposed to obtain polymer-grade ethylene from wasted refinery gas through a direct separation process, and heat pump-assisted thermal integration optimization (HPSCOAS) was carried out. The unique feature of the novel approach is that a new stripper and ethylene reabsorber follow the dry gas absorber to ensure ethylene recovery and methane content. An industrial model, shallow cooling oil absorption (SCOA), and concentration combined cold separation system of ethylene unit using wasted refinery gas was established to analyze the technology and environment. Based on the detailed process modeling and simulation results, the quantitative sustainability assessment of economy and environment based on product life cycle process is carried out. The results show that compared with the traditional process when the same product is obtained, the total annual cost of the HPSCOAS process is the lowest, which is 15.4% lower than that of the SCOA process and 6.1% lower than that of the SCOAS process. In addition, compared with the SCOA process and the HPSCOAS process, the SCOAS process has more environmental advantages. The non-renewable energy consumed by SCOAS is reduced by about 24.8% and 6.1%, respectively. The CO2 equivalent is reduced by about 38.6% and 23.7%.