化学键合聚乙烯亚胺涂层毛细管柱的快速制备及评价

O6; 以γ-缩水甘油醚丙基三甲氧基硅烷和聚乙烯亚胺,合成了具有三甲氧基硅烷活性基团的聚乙烯亚胺衍生物,并通过热处理使此高分子聚合物键合于石英毛细管内壁,成功制备了聚乙烯亚胺涂层毛细管柱.所制得的涂层柱能有效抑止电渗流和防止蛋白质在柱上的吸附.在pH 7.4的缓冲溶液中,碱性蛋白质的平均分离柱效为1.7×105理论塔板数/米,分析结果呈现出较好的重现性.该制柱方法快速简便,成功率高,涂层柱之间重现性良好....

Full description

Saved in:
Bibliographic Details
Published in:分析化学 2006, Vol.34 (z1), p.214-216
Main Authors: 陈卓铃, 刘亚雄, 丁国生, 包建民
Format: Article
Language:Chinese
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 216
container_issue z1
container_start_page 214
container_title 分析化学
container_volume 34
creator 陈卓铃
刘亚雄
丁国生
包建民
description O6; 以γ-缩水甘油醚丙基三甲氧基硅烷和聚乙烯亚胺,合成了具有三甲氧基硅烷活性基团的聚乙烯亚胺衍生物,并通过热处理使此高分子聚合物键合于石英毛细管内壁,成功制备了聚乙烯亚胺涂层毛细管柱.所制得的涂层柱能有效抑止电渗流和防止蛋白质在柱上的吸附.在pH 7.4的缓冲溶液中,碱性蛋白质的平均分离柱效为1.7×105理论塔板数/米,分析结果呈现出较好的重现性.该制柱方法快速简便,成功率高,涂层柱之间重现性良好.
doi_str_mv 10.3321/j.issn:0253-3820.2006.z1.053
format article
fullrecord <record><control><sourceid>wanfang_jour</sourceid><recordid>TN_cdi_wanfang_journals_fxhx2006z1053</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><wanfj_id>fxhx2006z1053</wanfj_id><sourcerecordid>fxhx2006z1053</sourcerecordid><originalsourceid>FETCH-wanfang_journals_fxhx2006z10533</originalsourceid><addsrcrecordid>eNpjYFAxNNAzNjYy1M_SyywuzrMyMDI11jW2MDLQMzIwMNOrMtQzMDVmYeCEi3Mw8BYXZyYZGBgaGphYmFpwMrg-7Zn2dO2yl1PWPZ3Q8aJx1pOdM583r3-ya9aL5l3PtjU93dj0bP3s57vbnq9b-Gz-xuezWp7uX_2yYf7Tjm1Pl7Q_7e96sb7lye7tPAysaYk5xam8UJqbQdXNNcTZQ7c8MS8tMS89Piu_tCgPKBOfVpFRAXJclSHQacbEqgMAyXZdLQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>化学键合聚乙烯亚胺涂层毛细管柱的快速制备及评价</title><source>ScienceDirect Journals</source><creator>陈卓铃 ; 刘亚雄 ; 丁国生 ; 包建民</creator><creatorcontrib>陈卓铃 ; 刘亚雄 ; 丁国生 ; 包建民</creatorcontrib><description>O6; 以γ-缩水甘油醚丙基三甲氧基硅烷和聚乙烯亚胺,合成了具有三甲氧基硅烷活性基团的聚乙烯亚胺衍生物,并通过热处理使此高分子聚合物键合于石英毛细管内壁,成功制备了聚乙烯亚胺涂层毛细管柱.所制得的涂层柱能有效抑止电渗流和防止蛋白质在柱上的吸附.在pH 7.4的缓冲溶液中,碱性蛋白质的平均分离柱效为1.7×105理论塔板数/米,分析结果呈现出较好的重现性.该制柱方法快速简便,成功率高,涂层柱之间重现性良好.</description><identifier>ISSN: 0253-3820</identifier><identifier>DOI: 10.3321/j.issn:0253-3820.2006.z1.053</identifier><language>chi</language><publisher>天津大学药物科学与技术学院,天津,300072</publisher><ispartof>分析化学, 2006, Vol.34 (z1), p.214-216</ispartof><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://www.wanfangdata.com.cn/images/PeriodicalImages/fxhx/fxhx.jpg</thumbnail><link.rule.ids>314,780,784,4022,27922,27923,27924</link.rule.ids></links><search><creatorcontrib>陈卓铃</creatorcontrib><creatorcontrib>刘亚雄</creatorcontrib><creatorcontrib>丁国生</creatorcontrib><creatorcontrib>包建民</creatorcontrib><title>化学键合聚乙烯亚胺涂层毛细管柱的快速制备及评价</title><title>分析化学</title><description>O6; 以γ-缩水甘油醚丙基三甲氧基硅烷和聚乙烯亚胺,合成了具有三甲氧基硅烷活性基团的聚乙烯亚胺衍生物,并通过热处理使此高分子聚合物键合于石英毛细管内壁,成功制备了聚乙烯亚胺涂层毛细管柱.所制得的涂层柱能有效抑止电渗流和防止蛋白质在柱上的吸附.在pH 7.4的缓冲溶液中,碱性蛋白质的平均分离柱效为1.7×105理论塔板数/米,分析结果呈现出较好的重现性.该制柱方法快速简便,成功率高,涂层柱之间重现性良好.</description><issn>0253-3820</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNpjYFAxNNAzNjYy1M_SyywuzrMyMDI11jW2MDLQMzIwMNOrMtQzMDVmYeCEi3Mw8BYXZyYZGBgaGphYmFpwMrg-7Zn2dO2yl1PWPZ3Q8aJx1pOdM583r3-ya9aL5l3PtjU93dj0bP3s57vbnq9b-Gz-xuezWp7uX_2yYf7Tjm1Pl7Q_7e96sb7lye7tPAysaYk5xam8UJqbQdXNNcTZQ7c8MS8tMS89Piu_tCgPKBOfVpFRAXJclSHQacbEqgMAyXZdLQ</recordid><startdate>2006</startdate><enddate>2006</enddate><creator>陈卓铃</creator><creator>刘亚雄</creator><creator>丁国生</creator><creator>包建民</creator><general>天津大学药物科学与技术学院,天津,300072</general><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>2006</creationdate><title>化学键合聚乙烯亚胺涂层毛细管柱的快速制备及评价</title><author>陈卓铃 ; 刘亚雄 ; 丁国生 ; 包建民</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-wanfang_journals_fxhx2006z10533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>chi</language><creationdate>2006</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>陈卓铃</creatorcontrib><creatorcontrib>刘亚雄</creatorcontrib><creatorcontrib>丁国生</creatorcontrib><creatorcontrib>包建民</creatorcontrib><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>分析化学</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>陈卓铃</au><au>刘亚雄</au><au>丁国生</au><au>包建民</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>化学键合聚乙烯亚胺涂层毛细管柱的快速制备及评价</atitle><jtitle>分析化学</jtitle><date>2006</date><risdate>2006</risdate><volume>34</volume><issue>z1</issue><spage>214</spage><epage>216</epage><pages>214-216</pages><issn>0253-3820</issn><abstract>O6; 以γ-缩水甘油醚丙基三甲氧基硅烷和聚乙烯亚胺,合成了具有三甲氧基硅烷活性基团的聚乙烯亚胺衍生物,并通过热处理使此高分子聚合物键合于石英毛细管内壁,成功制备了聚乙烯亚胺涂层毛细管柱.所制得的涂层柱能有效抑止电渗流和防止蛋白质在柱上的吸附.在pH 7.4的缓冲溶液中,碱性蛋白质的平均分离柱效为1.7×105理论塔板数/米,分析结果呈现出较好的重现性.该制柱方法快速简便,成功率高,涂层柱之间重现性良好.</abstract><pub>天津大学药物科学与技术学院,天津,300072</pub><doi>10.3321/j.issn:0253-3820.2006.z1.053</doi></addata></record>
fulltext fulltext
identifier ISSN: 0253-3820
ispartof 分析化学, 2006, Vol.34 (z1), p.214-216
issn 0253-3820
language chi
recordid cdi_wanfang_journals_fxhx2006z1053
source ScienceDirect Journals
title 化学键合聚乙烯亚胺涂层毛细管柱的快速制备及评价
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T02%3A41%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wanfang_jour&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=%E5%8C%96%E5%AD%A6%E9%94%AE%E5%90%88%E8%81%9A%E4%B9%99%E7%83%AF%E4%BA%9A%E8%83%BA%E6%B6%82%E5%B1%82%E6%AF%9B%E7%BB%86%E7%AE%A1%E6%9F%B1%E7%9A%84%E5%BF%AB%E9%80%9F%E5%88%B6%E5%A4%87%E5%8F%8A%E8%AF%84%E4%BB%B7&rft.jtitle=%E5%88%86%E6%9E%90%E5%8C%96%E5%AD%A6&rft.au=%E9%99%88%E5%8D%93%E9%93%83&rft.date=2006&rft.volume=34&rft.issue=z1&rft.spage=214&rft.epage=216&rft.pages=214-216&rft.issn=0253-3820&rft_id=info:doi/10.3321/j.issn:0253-3820.2006.z1.053&rft_dat=%3Cwanfang_jour%3Efxhx2006z1053%3C/wanfang_jour%3E%3Cgrp_id%3Ecdi_FETCH-wanfang_journals_fxhx2006z10533%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rft_wanfj_id=fxhx2006z1053&rfr_iscdi=true