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Laser-induced Fluorescence Spectroscopy of NiCl in 12900-15000 cm-1

Laser-induced fluorescence excitation spectra of jet-cooled NiC1 molecules were recorded in the energy range of 12900-15000 cm-1. Six vibronic bands with rotational structure have been observed and assigned to the [13.0]2II3/2(v'=0-5)-X2II3/2(v"=0) transition progression. The relevant rotational con...

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Published in:Chinese journal of chemical physics 2012-12, Vol.25 (6), p.631-635
Main Authors: Qin, Cheng-bing, Zang, Jian-zheng, Zhang, Qun, Chen, Yang
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description Laser-induced fluorescence excitation spectra of jet-cooled NiC1 molecules were recorded in the energy range of 12900-15000 cm-1. Six vibronic bands with rotational structure have been observed and assigned to the [13.0]2II3/2(v'=0-5)-X2II3/2(v"=0) transition progression. The relevant rotational constants, significant isotopic shifts, and (equilibrium) molecular parameters have been determined. In addition, the lifetimes of the observed bands have also been measured.
doi_str_mv 10.1088/1674-0068/25/06/631-635
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subjects 分子参数
同位素位移
射流冷却
激光诱导荧光光谱
能量范围
荧光激发光谱
转动常数
转动结构
title Laser-induced Fluorescence Spectroscopy of NiCl in 12900-15000 cm-1
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