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La-EDTA coated Fe3O4 nanomaterial: Preparation and application in removal of phosphate from water
La-EDTA-Fe3O4 was prepared by a chemical co-precipitation method. The magnetic composite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). Furthermore, the adsorption properties of La-EDTA-Fe3O4 toward phosphate...
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Published in: | Journal of environmental sciences (China) 2013-02, Vol.25 (2), p.413-418 |
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container_title | Journal of environmental sciences (China) |
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creator | Yang, Jiao Zeng, Qingru Peng, Liang Lei, Ming Song, Huijuan Tie, Boqing Gu, Jidong |
description | La-EDTA-Fe3O4 was prepared by a chemical co-precipitation method. The magnetic composite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). Furthermore, the adsorption properties of La-EDTA-Fe3O4 toward phosphate in water were investigated. The uptake rate of phosphate in water by La-EDTA-Fe3O4 was 3-1000 times than that of EDTA-Fe3O4, and reached 97.8% at 7 hr. The adsorption process agreed well with the Freundlich model and kinetics studies showed that the adsorption of phosphate proceeds according to pseudo second-order adsorption kinetics. The maximum removal rate was achieved at pH 6.0–7.0. The La-EDTA-Fe3O4 had good adsorption properties and could be separated well from aqueous solution by a permanent magnet. Therefore, this nanomaterial has potential application for the removal of phosphate from large water bodies. |
doi_str_mv | 10.1016/S1001-0742(12)60014-X |
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The magnetic composite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). Furthermore, the adsorption properties of La-EDTA-Fe3O4 toward phosphate in water were investigated. The uptake rate of phosphate in water by La-EDTA-Fe3O4 was 3-1000 times than that of EDTA-Fe3O4, and reached 97.8% at 7 hr. The adsorption process agreed well with the Freundlich model and kinetics studies showed that the adsorption of phosphate proceeds according to pseudo second-order adsorption kinetics. The maximum removal rate was achieved at pH 6.0–7.0. The La-EDTA-Fe3O4 had good adsorption properties and could be separated well from aqueous solution by a permanent magnet. Therefore, this nanomaterial has potential application for the removal of phosphate from large water bodies.</description><identifier>ISSN: 1001-0742</identifier><identifier>EISSN: 1878-7320</identifier><identifier>DOI: 10.1016/S1001-0742(12)60014-X</identifier><identifier>PMID: 23596964</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>Adsorption ; Edetic Acid - chemistry ; Ferrosoferric Oxide - chemistry ; Fourier transforms ; Infrared spectroscopy ; La-EDTA-Fe3O4 ; magnetic materials ; Nanocomposites ; Nanomaterials ; Nanostructure ; Nanostructures - chemistry ; phosphate ; Phosphates ; Phosphates - chemistry ; Reaction kinetics ; Water - chemistry</subject><ispartof>Journal of environmental sciences (China), 2013-02, Vol.25 (2), p.413-418</ispartof><rights>2013 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences</rights><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c462t-645c586c146589fbd2fe06850b825a48b771613e91c3a0ff4273cf728b82614e3</citedby><cites>FETCH-LOGICAL-c462t-645c586c146589fbd2fe06850b825a48b771613e91c3a0ff4273cf728b82614e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://www.wanfangdata.com.cn/images/PeriodicalImages/jes-e/jes-e.jpg</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23596964$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Jiao</creatorcontrib><creatorcontrib>Zeng, Qingru</creatorcontrib><creatorcontrib>Peng, Liang</creatorcontrib><creatorcontrib>Lei, Ming</creatorcontrib><creatorcontrib>Song, Huijuan</creatorcontrib><creatorcontrib>Tie, Boqing</creatorcontrib><creatorcontrib>Gu, Jidong</creatorcontrib><title>La-EDTA coated Fe3O4 nanomaterial: Preparation and application in removal of phosphate from water</title><title>Journal of environmental sciences (China)</title><addtitle>J Environ Sci (China)</addtitle><description>La-EDTA-Fe3O4 was prepared by a chemical co-precipitation method. The magnetic composite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). Furthermore, the adsorption properties of La-EDTA-Fe3O4 toward phosphate in water were investigated. The uptake rate of phosphate in water by La-EDTA-Fe3O4 was 3-1000 times than that of EDTA-Fe3O4, and reached 97.8% at 7 hr. The adsorption process agreed well with the Freundlich model and kinetics studies showed that the adsorption of phosphate proceeds according to pseudo second-order adsorption kinetics. The maximum removal rate was achieved at pH 6.0–7.0. The La-EDTA-Fe3O4 had good adsorption properties and could be separated well from aqueous solution by a permanent magnet. Therefore, this nanomaterial has potential application for the removal of phosphate from large water bodies.</description><subject>Adsorption</subject><subject>Edetic Acid - chemistry</subject><subject>Ferrosoferric Oxide - chemistry</subject><subject>Fourier transforms</subject><subject>Infrared spectroscopy</subject><subject>La-EDTA-Fe3O4</subject><subject>magnetic materials</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Nanostructures - chemistry</subject><subject>phosphate</subject><subject>Phosphates</subject><subject>Phosphates - chemistry</subject><subject>Reaction kinetics</subject><subject>Water - chemistry</subject><issn>1001-0742</issn><issn>1878-7320</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqNkU9PFTEUxSdGI4h-BE1XBhcj_d-OG0MQlOQlmAAJu6avcyt9mWnHdh7Eb28fA25xde9Jf-eepKdp3hP8mWAijy4JxqTFitNDQj_JKnh786LZJ1rpVjGKX9b9Cdlr3pSywRhzgcXrZo8y0clO8v3Grmx7-u3qGLlkZ-jRGbALjqKNaaw6Bzt8QT8zTDbbOaSIbOyRnaYhuEWHiDKM6c4OKHk03aYy3VYj8jmN6H534m3zytuhwLvHedBcn51enfxoVxffz0-OV63jks6t5MIJLR3hUujOr3vqAUst8FpTYbleK0UkYdARxyz2nlPFnFdU13dJOLCD5uNy995Gb-Mvs0nbHGui2UAxQDFhmGLKK3i4gFNOv7dQZjOG4mAYbIS0LYbIjjKtOO6eRxkjWHdCqf9AKaOUSiYqKhbU5VRKBm-mHEab_xiCza5c81Cu2TVnCDUP5Zqb6vvwGLFdj9D_cz21WYGvCwD1n-8CZFNcgOigDxncbPoUnon4C5fnsHY</recordid><startdate>20130201</startdate><enddate>20130201</enddate><creator>Yang, Jiao</creator><creator>Zeng, Qingru</creator><creator>Peng, Liang</creator><creator>Lei, Ming</creator><creator>Song, Huijuan</creator><creator>Tie, Boqing</creator><creator>Gu, Jidong</creator><general>Elsevier B.V</general><general>School of Metallurgical Science and Technology, Central South University, Changsha 410083, China%Hunan Perochemical Vocational Technology College, Yueyang 414012, China</general><general>Department of Environmental Science(&)Engineering, Hunan Agricultural University, Changsha 410128, China%Department of Environmental Science(&)Engineering, Hunan Agricultural University, Changsha 410128, China</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope><scope>SOI</scope><scope>7X8</scope><scope>7SU</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20130201</creationdate><title>La-EDTA coated Fe3O4 nanomaterial: Preparation and application in removal of phosphate from water</title><author>Yang, Jiao ; Zeng, Qingru ; Peng, Liang ; Lei, Ming ; Song, Huijuan ; Tie, Boqing ; Gu, Jidong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c462t-645c586c146589fbd2fe06850b825a48b771613e91c3a0ff4273cf728b82614e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Adsorption</topic><topic>Edetic Acid - chemistry</topic><topic>Ferrosoferric Oxide - chemistry</topic><topic>Fourier transforms</topic><topic>Infrared spectroscopy</topic><topic>La-EDTA-Fe3O4</topic><topic>magnetic materials</topic><topic>Nanocomposites</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Nanostructures - chemistry</topic><topic>phosphate</topic><topic>Phosphates</topic><topic>Phosphates - chemistry</topic><topic>Reaction kinetics</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Jiao</creatorcontrib><creatorcontrib>Zeng, Qingru</creatorcontrib><creatorcontrib>Peng, Liang</creatorcontrib><creatorcontrib>Lei, Ming</creatorcontrib><creatorcontrib>Song, Huijuan</creatorcontrib><creatorcontrib>Tie, Boqing</creatorcontrib><creatorcontrib>Gu, Jidong</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Environment Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><collection>Environmental Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Journal of environmental sciences (China)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Jiao</au><au>Zeng, Qingru</au><au>Peng, Liang</au><au>Lei, Ming</au><au>Song, Huijuan</au><au>Tie, Boqing</au><au>Gu, Jidong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>La-EDTA coated Fe3O4 nanomaterial: Preparation and application in removal of phosphate from water</atitle><jtitle>Journal of environmental sciences (China)</jtitle><addtitle>J Environ Sci (China)</addtitle><date>2013-02-01</date><risdate>2013</risdate><volume>25</volume><issue>2</issue><spage>413</spage><epage>418</epage><pages>413-418</pages><issn>1001-0742</issn><eissn>1878-7320</eissn><abstract>La-EDTA-Fe3O4 was prepared by a chemical co-precipitation method. The magnetic composite was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). Furthermore, the adsorption properties of La-EDTA-Fe3O4 toward phosphate in water were investigated. The uptake rate of phosphate in water by La-EDTA-Fe3O4 was 3-1000 times than that of EDTA-Fe3O4, and reached 97.8% at 7 hr. The adsorption process agreed well with the Freundlich model and kinetics studies showed that the adsorption of phosphate proceeds according to pseudo second-order adsorption kinetics. The maximum removal rate was achieved at pH 6.0–7.0. The La-EDTA-Fe3O4 had good adsorption properties and could be separated well from aqueous solution by a permanent magnet. Therefore, this nanomaterial has potential application for the removal of phosphate from large water bodies.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>23596964</pmid><doi>10.1016/S1001-0742(12)60014-X</doi><tpages>6</tpages></addata></record> |
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subjects | Adsorption Edetic Acid - chemistry Ferrosoferric Oxide - chemistry Fourier transforms Infrared spectroscopy La-EDTA-Fe3O4 magnetic materials Nanocomposites Nanomaterials Nanostructure Nanostructures - chemistry phosphate Phosphates Phosphates - chemistry Reaction kinetics Water - chemistry |
title | La-EDTA coated Fe3O4 nanomaterial: Preparation and application in removal of phosphate from water |
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