Electrolytic reduction of mixed solid oxides in molten salts for energy efficient production of the TiNi alloy

Direct electrochemical reduction of mixed TiO2 and NiO powders to TiNi alloy has been successfully demonstrated in molten CaCl2 at 900℃ by constant voltage electrolysis. The electrolysis energy consumption was as low as 23.4 kWh/kg-TiNi, although the current efficiency was 20.5% in the preliminary e...

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Bibliographic Details
Published in:Chinese science bulletin 2006-10, Vol.51 (20), p.2535-2540
Main Authors: Zhu, Yong, Ma, Meng, Wang, Dihua, Jiang, Kai, Hu, Xiaohong, Jin, Xianbo, Chen, George Z.
Format: Article
Language:English
Subjects:
熔盐电解
电解还原
钛镍合金
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Summary:Direct electrochemical reduction of mixed TiO2 and NiO powders to TiNi alloy has been successfully demonstrated in molten CaCl2 at 900℃ by constant voltage electrolysis. The electrolysis energy consumption was as low as 23.4 kWh/kg-TiNi, although the current efficiency was 20.5% in the preliminary experiments. During the process, NiO was first reduced to Ni at high speed, accompanied by TiO2 being perovskitized to CaTiO3-x which was gradually reduced to Ni3Ti and TiNi, assisted by the depolarization of the preformed Ni. The cell voltage for preparation of the TiNi alloy was lower than that for Ti. Adjusting the cell voltage not only affected the reduction speed, but also offered a convenient access to the preparation of the nickel/perovskite composite.
ISSN:1001-6538
1861-9541
DOI:10.1007/s11434-006-2105-1