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Adsorption of 2,4-Dichlorophenol from Aqueous Solution onto Microwave Modified Activated Carbon: Kinetics and Equilibrium
Batch experiments were conducted to investigate the adsorption of 2,4-dichlorophenol (2,4-DCP) onto microwave modified activated carbon (AC) at three different temperatures (303 K, 313 K and 323 K). Adsorption isotherms, kinetics, and thermodynamics of the adsorption process were explored. Equilibri...
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Published in: | Transactions of Tianjin University 2009-12, Vol.15 (6), p.408-414 |
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description | Batch experiments were conducted to investigate the adsorption of 2,4-dichlorophenol (2,4-DCP) onto microwave modified activated carbon (AC) at three different temperatures (303 K, 313 K and 323 K). Adsorption isotherms, kinetics, and thermodynamics of the adsorption process were explored. Equilibrium data were fitted into Langmuir and Freundlich equations, and the result reveals that the Freundlich isotherm model fits better than the Langmuir model. Three simplified kinetic models: pseudo-first-order, pseudo-second-order, and intrapartiele diffusion equations were adopted to examine the mechanism of the adsorption process, and the pseudo-second-order kinetic model proved to be the best in describing the adsorption data. The thermodynamic parameters of the adsorption process were estimated, showing that the adsorption of 2,4-DCP was exothermic and spontaneous, and the adsorption studied in this paper can be assigned to a physisorption mechanism. |
doi_str_mv | 10.1007/s12209-009-0071-9 |
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Adsorption isotherms, kinetics, and thermodynamics of the adsorption process were explored. Equilibrium data were fitted into Langmuir and Freundlich equations, and the result reveals that the Freundlich isotherm model fits better than the Langmuir model. Three simplified kinetic models: pseudo-first-order, pseudo-second-order, and intrapartiele diffusion equations were adopted to examine the mechanism of the adsorption process, and the pseudo-second-order kinetic model proved to be the best in describing the adsorption data. The thermodynamic parameters of the adsorption process were estimated, showing that the adsorption of 2,4-DCP was exothermic and spontaneous, and the adsorption studied in this paper can be assigned to a physisorption mechanism.</description><identifier>ISSN: 1006-4982</identifier><identifier>EISSN: 1995-8196</identifier><identifier>DOI: 10.1007/s12209-009-0071-9</identifier><language>eng</language><publisher>Heidelberg: Tianjin University</publisher><subject>Engineering ; Freundlich方程 ; Humanities and Social Sciences ; Langmuir模型 ; Mechanical Engineering ; multidisciplinary ; Science ; 二氯苯酚 ; 动力学模型 ; 吸附等温线 ; 改性活性炭</subject><ispartof>Transactions of Tianjin University, 2009-12, Vol.15 (6), p.408-414</ispartof><rights>Tianjin University and Springer Berlin Heidelberg 2009</rights><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2673-aa82e29b36197136ea7bdac48c1bdd70f0e8ece9924a9b57005459b0ea9c9a7d3</citedby><cites>FETCH-LOGICAL-c2673-aa82e29b36197136ea7bdac48c1bdd70f0e8ece9924a9b57005459b0ea9c9a7d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/85460X/85460X.jpg</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>邹学权 万先凯 史惠祥 汪大翚</creatorcontrib><title>Adsorption of 2,4-Dichlorophenol from Aqueous Solution onto Microwave Modified Activated Carbon: Kinetics and Equilibrium</title><title>Transactions of Tianjin University</title><addtitle>Trans. Tianjin Univ</addtitle><addtitle>Transactions of Tianjin University</addtitle><description>Batch experiments were conducted to investigate the adsorption of 2,4-dichlorophenol (2,4-DCP) onto microwave modified activated carbon (AC) at three different temperatures (303 K, 313 K and 323 K). Adsorption isotherms, kinetics, and thermodynamics of the adsorption process were explored. Equilibrium data were fitted into Langmuir and Freundlich equations, and the result reveals that the Freundlich isotherm model fits better than the Langmuir model. Three simplified kinetic models: pseudo-first-order, pseudo-second-order, and intrapartiele diffusion equations were adopted to examine the mechanism of the adsorption process, and the pseudo-second-order kinetic model proved to be the best in describing the adsorption data. The thermodynamic parameters of the adsorption process were estimated, showing that the adsorption of 2,4-DCP was exothermic and spontaneous, and the adsorption studied in this paper can be assigned to a physisorption mechanism.</description><subject>Engineering</subject><subject>Freundlich方程</subject><subject>Humanities and Social Sciences</subject><subject>Langmuir模型</subject><subject>Mechanical Engineering</subject><subject>multidisciplinary</subject><subject>Science</subject><subject>二氯苯酚</subject><subject>动力学模型</subject><subject>吸附等温线</subject><subject>改性活性炭</subject><issn>1006-4982</issn><issn>1995-8196</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kMtuFDEQRVsIJJLAB7CzWKdD2f1wezmaPIiSiAWwtsqPnvHQY8_Y3Xkof8K35J_4hZh0JHYsSnUX59ZV3aL4ROGEAvAviTIGooSX4bQUb4oDKkRTdlS0b7MGaMtadOx9cZjSBqAWGTsoHhcmhbgbXfAk9IQd1-Wp0-shxLBbWx8G0sewJYv9ZMOUyPcwTDPrx0BunI7hDm8tuQnG9c4astCju8UxqyVGFfyfp9_kynk7Op0IekPO9pMbnIpu2n4o3vU4JPvxdR8VP8_Pfiy_ltffLi6Xi-tSs5ZXJWLHLBOqaqngtGotcmVQ152myhgOPdjOaisEq1GohgM0dSMUWBRaIDfVUXE8371D36NfyU2Yos-JcnToN-b-XknLcnXQAlQZpzOen0sp2l7uottifJAU5N-y5Vy2hJfhVIrsYbMnZdavbPyX8T_T59egdfCrffZJhfpX7wYrK8ZqznhTPQMgFZCM</recordid><startdate>200912</startdate><enddate>200912</enddate><creator>邹学权 万先凯 史惠祥 汪大翚</creator><general>Tianjin University</general><general>Institute of Environmental Science and Technology, Zhejiang University, Hangzhou 310027, China</general><general>Zhejiang Academy of Science and Technology for Inspection and Quarantine, Hangzhou 310000, China%Institute of Environmental Science and Technology, Zhejiang University, Hangzhou 310027, China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W94</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>200912</creationdate><title>Adsorption of 2,4-Dichlorophenol from Aqueous Solution onto Microwave Modified Activated Carbon: Kinetics and Equilibrium</title><author>邹学权 万先凯 史惠祥 汪大翚</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2673-aa82e29b36197136ea7bdac48c1bdd70f0e8ece9924a9b57005459b0ea9c9a7d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Engineering</topic><topic>Freundlich方程</topic><topic>Humanities and Social Sciences</topic><topic>Langmuir模型</topic><topic>Mechanical Engineering</topic><topic>multidisciplinary</topic><topic>Science</topic><topic>二氯苯酚</topic><topic>动力学模型</topic><topic>吸附等温线</topic><topic>改性活性炭</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>邹学权 万先凯 史惠祥 汪大翚</creatorcontrib><collection>维普_期刊</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>维普中文期刊数据库</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Transactions of Tianjin University</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>邹学权 万先凯 史惠祥 汪大翚</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of 2,4-Dichlorophenol from Aqueous Solution onto Microwave Modified Activated Carbon: Kinetics and Equilibrium</atitle><jtitle>Transactions of Tianjin University</jtitle><stitle>Trans. Tianjin Univ</stitle><addtitle>Transactions of Tianjin University</addtitle><date>2009-12</date><risdate>2009</risdate><volume>15</volume><issue>6</issue><spage>408</spage><epage>414</epage><pages>408-414</pages><issn>1006-4982</issn><eissn>1995-8196</eissn><abstract>Batch experiments were conducted to investigate the adsorption of 2,4-dichlorophenol (2,4-DCP) onto microwave modified activated carbon (AC) at three different temperatures (303 K, 313 K and 323 K). Adsorption isotherms, kinetics, and thermodynamics of the adsorption process were explored. Equilibrium data were fitted into Langmuir and Freundlich equations, and the result reveals that the Freundlich isotherm model fits better than the Langmuir model. Three simplified kinetic models: pseudo-first-order, pseudo-second-order, and intrapartiele diffusion equations were adopted to examine the mechanism of the adsorption process, and the pseudo-second-order kinetic model proved to be the best in describing the adsorption data. The thermodynamic parameters of the adsorption process were estimated, showing that the adsorption of 2,4-DCP was exothermic and spontaneous, and the adsorption studied in this paper can be assigned to a physisorption mechanism.</abstract><cop>Heidelberg</cop><pub>Tianjin University</pub><doi>10.1007/s12209-009-0071-9</doi><tpages>7</tpages></addata></record> |
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subjects | Engineering Freundlich方程 Humanities and Social Sciences Langmuir模型 Mechanical Engineering multidisciplinary Science 二氯苯酚 动力学模型 吸附等温线 改性活性炭 |
title | Adsorption of 2,4-Dichlorophenol from Aqueous Solution onto Microwave Modified Activated Carbon: Kinetics and Equilibrium |
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