Preparation and photochemical behavior of a cationic azobenzene dye-montmorillonite intercalation compound

Montmorillonite/cationic azobenzene dye(p-(δ-triethylammoniobutoxy)-p'-methyl-azobenzene bromide) intercalation compounds were prepared by the conventional ion exchange method. As compared with that of pure cationic azo-dye, the thermal stability of the intercalated dye was greatly enhanced, an...

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Bibliographic Details
Published in:Journal of Wuhan University of Technology. Materials science edition 2007-09, Vol.22 (3), p.466-469
Main Authors: Wan, Tao, Xu, Huihua, Yuan, Yi, He, Wenqiong
Format: Article
Language:English
Subjects:
Dyes
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Summary:Montmorillonite/cationic azobenzene dye(p-(δ-triethylammoniobutoxy)-p'-methyl-azobenzene bromide) intercalation compounds were prepared by the conventional ion exchange method. As compared with that of pure cationic azo-dye, the thermal stability of the intercalated dye was greatly enhanced, and the absorption band corresponding to azobenzene group in intercalated dye shifted towards longer wave length by 38 nm. This could be ascribed to the strong conjugation of cationic azo-dye supramolecular order structure(J cluster) confined in a nanoscale space of montmorillonite interlayer gallery. UV/vis spectra data show that the intercalated azo dye in the montmorillonite interlayer space exhibited reversible trans-to-cis photoisomerization and daylight cis-to-trans back reaction. FTIR indicates the successful intercalation of cationic azo-dye into the montmorillonite interlayer.[PUBLICATION ABSTRACT]
ISSN:1000-2413
1993-0437
DOI:10.1007/s11595-006-3466-7