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PS-HQ: More convenient in situ polymeric cocatalyst for the PdCl2-catalyzed acetalization in supercritical carbon dioxide

O6; Polystyrene-supported hydroquinone (PS-HQ) is presented as an in situ polymeric cocatalyst to replace polystyrene-supported benzoquinone (PS-BQ) in the PdCl2-catalyzed acetalization of methyl acrylate with methanol in supercritical carbon dioxide (scCO2) under oxygen atmosphere. Due to deletion...

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Bibliographic Details
Published in:Chinese chemical letters 2007-08, Vol.18 (8), p.969-972
Main Authors: Wang, Zhao Yang, Jiang, Huan Feng, Qi, Chao Rong, Shen, Yan Xia, Yang, Shao Rong
Format: Article
Language:English
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Summary:O6; Polystyrene-supported hydroquinone (PS-HQ) is presented as an in situ polymeric cocatalyst to replace polystyrene-supported benzoquinone (PS-BQ) in the PdCl2-catalyzed acetalization of methyl acrylate with methanol in supercritical carbon dioxide (scCO2) under oxygen atmosphere. Due to deletion of H2O2 oxidation step, PS-HQ is more convenient and relatively inexpensive.
ISSN:1001-8417
DOI:10.1016/j.cclet.2007.05.026