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PS-HQ: More convenient in situ polymeric cocatalyst for the PdCl2-catalyzed acetalization in supercritical carbon dioxide
O6; Polystyrene-supported hydroquinone (PS-HQ) is presented as an in situ polymeric cocatalyst to replace polystyrene-supported benzoquinone (PS-BQ) in the PdCl2-catalyzed acetalization of methyl acrylate with methanol in supercritical carbon dioxide (scCO2) under oxygen atmosphere. Due to deletion...
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Published in: | Chinese chemical letters 2007-08, Vol.18 (8), p.969-972 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites |
Online Access: | Get full text |
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Summary: | O6; Polystyrene-supported hydroquinone (PS-HQ) is presented as an in situ polymeric cocatalyst to replace polystyrene-supported benzoquinone (PS-BQ) in the PdCl2-catalyzed acetalization of methyl acrylate with methanol in supercritical carbon dioxide (scCO2) under oxygen atmosphere. Due to deletion of H2O2 oxidation step, PS-HQ is more convenient and relatively inexpensive. |
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ISSN: | 1001-8417 |
DOI: | 10.1016/j.cclet.2007.05.026 |