Layered zirconium phosphate-supported metalloporphyrin: Synthesis and catalytic application

This paper reports a new route for the preparation of layered alpha-zirconium phosphate (α-ZrP)-supported metalloporphyrin MnTMPyP. MnTMPyP was intercalated into α-ZrP using α-ZrP·BA ( i.e. pre-intercalated bultylamine was arranged by a monolayer mode in α-ZrP) as a starting material. The catalytic...

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Bibliographic Details
Published in:Chinese chemical letters 2008-11, Vol.19 (11), p.1330-1332
Main Authors: Wang, Hai Yan, Ji, Wei Dong, Han, Da Xiong
Format: Article
Language:English
Subjects:
Catalysis
Intercalation
Layered α-ZrP
MnTMPyP
Supported material
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Summary:This paper reports a new route for the preparation of layered alpha-zirconium phosphate (α-ZrP)-supported metalloporphyrin MnTMPyP. MnTMPyP was intercalated into α-ZrP using α-ZrP·BA ( i.e. pre-intercalated bultylamine was arranged by a monolayer mode in α-ZrP) as a starting material. The catalytic activity of the supported material for homovanillic acid (HVA) oxidation was investigated. The results showed a promising layered material-supported catalyst in catalytic system.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2008.07.024