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A zinc(II) MOF based on secondary building units of infinite wavy-shaped chain exhibiting obvious luminescent sense effects
A metal-organic framework (1) based on a wavy and infinite chain-shaped secondary building unit was constructed and it exhibits palpable luminescent sense effects for DMF and DMAC. [Display omitted] A new metal-organic framework (MOF), {[Zn7(BPS)4(OH)6(H2O)2]·5H2O]n} (1), (H2BPS=4,4′-bibenzoic acid-...
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Published in: | Chinese chemical letters 2019-02, Vol.30 (2), p.499-501 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A metal-organic framework (1) based on a wavy and infinite chain-shaped secondary building unit was constructed and it exhibits palpable luminescent sense effects for DMF and DMAC.
[Display omitted]
A new metal-organic framework (MOF), {[Zn7(BPS)4(OH)6(H2O)2]·5H2O]n} (1), (H2BPS=4,4′-bibenzoic acid-2,2′-sulfone), based on a wavy and infinite chain-shaped secondary building units, has been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and further confirmed by PXRD, TGA and IR spectrum. The solid-state emission spectra reveal that compound 1 presents strong luminescence emission bands at room temperature. The fluorescent properties of compound 1 in diverse organic solvents indicated that 1 has palpable luminescent sense effects for DMF and DMAC. |
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ISSN: | 1001-8417 1878-5964 |
DOI: | 10.1016/j.cclet.2018.05.001 |