Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters

An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical condi...

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Bibliographic Details
Published in:Chinese chemical letters 2022-03, Vol.33 (3), p.1555-1558
Main Authors: Dai, Jian-Jun, Teng, Xin-Xin, Fang, Wen, Xu, Jun, Xu, Hua-Jian
Format: Article
Language:English
Subjects:
Alkyl boronic esters
Borylation
Decarboxylation
Electrochemical
Redox active esters
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Summary:An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical conditions. This reaction exhibits broad substrate scope, good functional group tolerability, and easy scalability. An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. [Display omitted]
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2021.09.011