Tailoring biochar by PHP towards the oxygenated functional groups (OFGs)-rich surface to improve adsorption performance

• Published in: Chinese chemical letters 2022-06, Vol.33 (6), p.3097-3100
• Main Authors: Xiong, Xinyue, Liu, Zhanglin, Zhao, Li, Huang, Mei, Dai, Lichun, Tian, Dong, Zou, Jianmei, Zeng, Yongmei, Hu, Jinguang, Shen, Fei
• Format: Article
• Language: English
• Subjects: Biochar; Hydrogen peroxide; Oxidative modification; Oxygenated functional groups; Phosphoric acid
• ISSN: 1001-8417; 1878-5964
• DOI: 10.1016/j.cclet.2021.09.099

In this work, a modification method of H3PO4 plus H2O2 (PHP) was introduced to targetedly form abundant oxygenated functional groups (OFGs) on biochar, and methylene blue (MB) was employed as a model pollutant for adsorption to reflect the modification performance. Results indicated that parent biochars, especially derived from lower temperatures, substantially underwent oxidative modification by PHP, and OFGs were targetedly produced. Correspondingly, approximately 21.5-fold MB adsorption capacity was achieved by PHP-modified biochar comparing with its parent biochar. To evaluate the compatibility of PHP-modification, coefficient of variation (CV) based on MB adsorption capacity by the biochar from various precursors was calculated, in which the CV of PHP-modified biochars was 0.0038 comparing to 0.64 of the corresponding parent biochars. These results suggested that the PHP method displayed the excellent feedstock compatibility on biochar modification. The maximum MB adsorption capacity was 454.1 mg/g when the H3PO4 and H2O2 fraction in PHP were 65.2% and 7.0%; the modification was further intensified by promoting temperature and duration. Besides, average 94.5% H3PO4 was recovered after 10-batch modification, implying 1.0 kg H3PO4 (85%) in PHP can maximally modify 2.37 kg biochar. Overall, this work offered a novel method to tailor biochar towards OFGs-rich surface for efficient adsorption. H3PO4 plus H2O2 (PHP) was introduced to targetedly modify biochar for rich-OFGs surface; the adsorption of model pollutant (methylene blue) using the PHP-modified biochar can be significantly promoted by 21.5 folds comparing with the corresponding parent biochar. [Display omitted]