High-efficiency circularly polarized emission from liquid-crystalline platinum complexes

• Published in: Chinese chemical letters 2023-06, Vol.34 (6), p.107934-314, Article 107934
• Main Authors: Fan, Peng, Fang, Zhou, Wang, Shengyue, Dong, Qiwei, Xiao, Chen, McEllin, Alice J., Bruce, Duncan W., Zhu, Weiguo, Wang, Yafei
• Format: Article
• Language: English
• Subjects: Circularly polarized emission; Liquid-crystalline; Organic light-emitting diodes; Platinum complex
• ISSN: 1001-8417; 1878-5964
• DOI: 10.1016/j.cclet.2022.107934

Realizing both a high emission efficiency and luminescence dissymmetry factor (glum) in circularly polarized solution processable organic light-emitting diodes (CP-OLEDs) remains a significant challenge. In this contribution, two chiral phosphorescent liquid crystals based on cyclometalated platinum complexes are prepared, in which the chiral s-2-methyl-1‑butyl group is introduced into the cyclometalating ligand and the mesogenic fragment is attached to the periphery of the ancillary ligand. The platinum complexes exhibit both smectic and chiral nematic phases as evidenced by polarized optical microscopy, differential scanning calorimetry and small-angle X-ray diffraction. Remarkably, a high photoluminescent quantum efficiency of over 78% and clear circularly polarized luminescent signal with gPL of about 10–2 are observed for the complexes. Further, solution-processed CP-OLEDs show maximum external quantum efficiencies (EQE) of over 15% and strong circularly polarized electroluminescent signals with a gEL ≈ 10–2. This research demonstrates that both liquid crystallinity and the number of chiral centers play key roles in improving the chiroptical property, paving the way for a new approach for the design of high-efficiency CPL emitters. Two chiral phosphorescent liquid crystal based on cyclometalated platinum complexes are prepared, in which the chiral S-2-methyl-1‑butyl group is introduced into the cyclometalating ligand and the mesogenic fragment is attached to the periphery of the ancillary ligand. High photoluminescent quantum efficiency of over 78% and clear CPL signal with gPL of about 10–2 are observed for the complexes. Remarkably, solution-processed CP-OLEDs show maximum external quantum efficiencies (EQE) of over 15% and strong CPEL signals with a gEL ≈ 10–2. [Display omitted]