Preparation of multicolor carbon dots with thermally turn-on fluorescence for multidimensional information encryption

• Published in: Chinese chemical letters 2024-01, Vol.35 (1), p.108420-347, Article 108420
• Main Authors: Wang, Chan, Huang, Jianfeng, He, Yimin, Ran, Guoxia, Song, Qijun
• Format: Article
• Language: English
• Subjects: Advanced anti-counterfeiting; Carbon dots; Full-color fluorescence; Precursor-oriented structure; Turn-on thermosensitivity
• ISSN: 1001-8417; 1878-5964
• DOI: 10.1016/j.cclet.2023.108420

Carbon dots (CDs) with superior fluorescence properties have attracted a growing number of research interests in anti-counterfeiting. However, the preparation of CDs with thermally turn-on fluorescence and full-color-emitting in visible spectrum is still a big challenge due to the complicated reaction mechanism in the formation of CDs. Here, a simple precursor-oriented strategy for the preparation of multicolor CDs with heat-stimuli turn-on fluorescence is reported. Comprehensive experimental characterizations and theoretical calculations revealed that the emission wavelength of CDs can be readily tuned from 460 nm to 654 nm with selected precursors, which was ascribed to the extent of conjugated sp2-domains (core states) and the amount of oxygen- and nitrogen-containing groups bound to sp2-domains (surface states). After simply mixing two or three kinds of CDs, a full-color range of fluorescence emission was realized, and the CDs-based fluorescence inks were successfully fabricated. Particularly, all the printed patterns from the inkjet exhibited a thermal-induced enhancement in fluorescence. On this basis, combining CDs with heating-induced “turn-off” fluorescence materials can lead to multidimensional and multistage encryption. These results demonstrate that the thermochromic and photochromic CDs with much more enhanced security exhibit promising application in data storage and encryption. [Display omitted] Multicolor carbon dots (CDs) with turn-on thermochromic characteristics are developed by scrutinizing selection of precursors, and the resulting CDs exhibit much more enhanced security and promising application in data storage and encryption