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Electroluminescent Property of A Novel Co-Doped Rare Earth Complex

A novel co-doped rare earth complex Gd0.5Eu0.5(TTA)3Dipy was synthesized and chosen as the emitter material in the organic electroluminescent device ITO/PVK:Gd0.5 Eu0.5 (TTA)3Dipy/PBD/A1. It was proved that there was Forster energy transfer from Gd^3+ to Eu^3+. The electroluminescent mechanism of th...

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Bibliographic Details
Published in:Journal of rare earths 2007, Vol.25 (5), p.558-561
Main Author: 宋林 徐征 赵谡玲 吕玉光 符雅丽 黄金昭 贾晓昀 张敬畅
Format: Article
Language:English
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Summary:A novel co-doped rare earth complex Gd0.5Eu0.5(TTA)3Dipy was synthesized and chosen as the emitter material in the organic electroluminescent device ITO/PVK:Gd0.5 Eu0.5 (TTA)3Dipy/PBD/A1. It was proved that there was Forster energy transfer from Gd^3+ to Eu^3+. The electroluminescent mechanism of the device was proposed by measuring and analyzing the emission and the excitation spectra of the emissive layer. Gd^3+ might play the role of promoting the en- ergy transfer from PVK to Eu^3+ and inhibiting an intrinsic luminescence of PVK. The device displayed red light with good monochromaticity. The possible energy transfer process of the device was preliminarily discussed.
ISSN:1002-0721
2509-4963
DOI:10.1016/S1002-0721(07)60562-6