Adsorption properties of Ag(I), Au(III), Pd(II) and Pt(IV) ions on commercial 717 anion-exchange resin

The adsorption properties of the four precious metal ions (Ag(I), Au(II), Pd(III) and Pt(IV)) on the commercial Cl −-form 717 strongly basic anion-exchange resin were studied in detail. The effects of the contact time, solution acidity, and concentrations of Cl − and Pb 2+ ions on the adsorption pro...

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Bibliographic Details
Published in:Transactions of Nonferrous Metals Society of China 2009-12, Vol.19 (6), p.1509-1513
Main Authors: LIU, Peng, LIU, Guang-feng, CHEN, Da-lin, CHENG, Shao-yi, TANG, Ning
Format: Article
Language:English
Subjects:
adsorption
commercial resin
optimization
precious metal ions
reduction
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Summary:The adsorption properties of the four precious metal ions (Ag(I), Au(II), Pd(III) and Pt(IV)) on the commercial Cl −-form 717 strongly basic anion-exchange resin were studied in detail. The effects of the contact time, solution acidity, and concentrations of Cl − and Pb 2+ ions on the adsorption properties were studied by the batch method. Then, the column method was conducted under the optimized adsorption conditions (pH=3.0). The effects of the sample loading flow rate and the length-to-diameter ratios of the columns were investigated. The precious metal ions adsorbed could not be eluted completely after the saturated adsorption because the precious metal ions were found to be reduced to their metallic states during the adsorption process. So, it is recommended that the commercial Cl −-form 717 strongly basic anion-exchange resin should be decomposed directly to recovery the precious metals after the saturated adsorption.
ISSN:1003-6326
DOI:10.1016/S1003-6326(09)60061-3