Activation of Molecular Nitrogen: Coordination, Cleavage and Functionalization of N2 Mediated By Metal Complexes

Recent developments in the activation and reactivity of coordinated dinitrogen are reviewed. Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogen‐nitrogen bonds and N2 cleavage reactions are discussed. Protonation reactions to form ammonia or hydrazido derivatives are c...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2003-09, Vol.345 (9-10), p.1061-1076
Main Authors: Shaver, Michael P., Fryzuk, Michael D.
Format: Article
Language:English
Subjects:
activation
coordination modes
dinitrogen
metal complexes
nitrogen fixation
reactivity
Online Access:Get full text
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Summary:Recent developments in the activation and reactivity of coordinated dinitrogen are reviewed. Examples of weakly activated dinitrogen metal complexes, strongly reduced nitrogen‐nitrogen bonds and N2 cleavage reactions are discussed. Protonation reactions to form ammonia or hydrazido derivatives are covered along with processes in which nitrogen‐boron, nitrogen‐silicon or nitrogen‐carbon bonds can form. Although this review builds on previous publications, a general introduction to this field is included.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200303081