Cover Picture: Two-Dimensional Triangular and Square Heterometallic Clusters: Influence of the Closed-Shell d10 Electronic Configuration (Angew. Chem. Int. Ed. 51/2009)

Guilded Rafts …︁ can be formed by heterometallic clusters. In their Communication on page 9663 ff., P. Braunstein, M. Bénard et al. describe the synthesis, structure, and theoretical analysis of a unique series of 2D raft mixed‐metal clusters of the type {M[m]}n (M=Cu, n=3; M=Ag, Au, n=4; the bridgi...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2009-12, Vol.48 (51), p.9567-9567
Main Authors: Sculfort, Sabrina, Croizat, Pierre, Messaoudi, Abdelatif, Bénard, Marc, Rohmer, Marie-Madeleine, Welter, Richard, Braunstein, Pierre
Format: Article
Language:English
Subjects:
coinage metals
density functional calculations
heterometallic clusters
metal-metal interactions
metallophilic interactions
Online Access:Get full text
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Summary:Guilded Rafts …︁ can be formed by heterometallic clusters. In their Communication on page 9663 ff., P. Braunstein, M. Bénard et al. describe the synthesis, structure, and theoretical analysis of a unique series of 2D raft mixed‐metal clusters of the type {M[m]}n (M=Cu, n=3; M=Ag, Au, n=4; the bridging metalloligand [m] is {MoCp(CO)3}). Intramolecular, metallophilic d10⋅⋅⋅d10 interactions occur in the ν2‐triangular (M=Cu) or ν2‐square (M=Ag, Au) structures of the metal cores.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905603