Cover Picture: Two-Dimensional Triangular and Square Heterometallic Clusters: Influence of the Closed-Shell d10 Electronic Configuration (Angew. Chem. Int. Ed. 51/2009)

Guilded Rafts …︁ can be formed by heterometallic clusters. In their Communication on page 9663 ff., P. Braunstein, M. Bénard et al. describe the synthesis, structure, and theoretical analysis of a unique series of 2D raft mixed‐metal clusters of the type {M[m]}n (M=Cu, n=3; M=Ag, Au, n=4; the bridgi...

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Published in:Angewandte Chemie International Edition 2009-12, Vol.48 (51), p.9567-9567
Main Authors: Sculfort, Sabrina, Croizat, Pierre, Messaoudi, Abdelatif, Bénard, Marc, Rohmer, Marie-Madeleine, Welter, Richard, Braunstein, Pierre
Format: Article
Language:English
Subjects:
coinage metals
density functional calculations
heterometallic clusters
metal-metal interactions
metallophilic interactions
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container_issue 51
container_start_page 9567
container_title Angewandte Chemie International Edition
container_volume 48
creator Sculfort, Sabrina
Croizat, Pierre
Messaoudi, Abdelatif
Bénard, Marc
Rohmer, Marie-Madeleine
Welter, Richard
Braunstein, Pierre
description Guilded Rafts …︁ can be formed by heterometallic clusters. In their Communication on page 9663 ff., P. Braunstein, M. Bénard et al. describe the synthesis, structure, and theoretical analysis of a unique series of 2D raft mixed‐metal clusters of the type {M[m]}n (M=Cu, n=3; M=Ag, Au, n=4; the bridging metalloligand [m] is {MoCp(CO)3}). Intramolecular, metallophilic d10⋅⋅⋅d10 interactions occur in the ν2‐triangular (M=Cu) or ν2‐square (M=Ag, Au) structures of the metal cores.
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subjects coinage metals
density functional calculations
heterometallic clusters
metal-metal interactions
metallophilic interactions
title Cover Picture: Two-Dimensional Triangular and Square Heterometallic Clusters: Influence of the Closed-Shell d10 Electronic Configuration (Angew. Chem. Int. Ed. 51/2009)
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