PdII-Catalyzed Highly Selective Arylation of Allyl Esters via CH Functionalization of Unreactive Arenes with Retention of the Traditional Leaving Group

A highly selective Fujiwara–Moritani oxidative Heck reaction of allyl esters with unreactive arenes via CH bond activation was developed, in which β‐H elimination is highly chemo‐, regio‐ and stereoselective. Moreover, even electron‐deficient arenes are tolerated in this type of CH activation....

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Published in:Chemistry, an Asian journal an Asian journal, 2010-05, Vol.5 (5), p.1090-1093
Main Authors: Pan, Delin, Yu, Miao, Chen, Wei, Jiao, Ning
Format: Article
Language:English
Subjects:
allylic compounds
heck reaction
palladium
regioselectivity
silver
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creator Pan, Delin
Yu, Miao
Chen, Wei
Jiao, Ning
description A highly selective Fujiwara–Moritani oxidative Heck reaction of allyl esters with unreactive arenes via CH bond activation was developed, in which β‐H elimination is highly chemo‐, regio‐ and stereoselective. Moreover, even electron‐deficient arenes are tolerated in this type of CH activation.
doi_str_mv 10.1002/asia.200900558
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source Wiley-Blackwell Read & Publish Collection
subjects allylic compounds
heck reaction
palladium
regioselectivity
silver
title PdII-Catalyzed Highly Selective Arylation of Allyl Esters via CH Functionalization of Unreactive Arenes with Retention of the Traditional Leaving Group
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