Cover Feature: Self‐Assembly Process of a Pd2L4 Capsule: Steric Interactions between Neighboring Components Favor the Formation of Large Intermediates (Chem. Eur. J. 16/2018)

The self‐assembly of a Pd2L4 capsule consisting of Pd(II) ions and ditopic ligands comprising an anthracene panel takes place mainly through three pathways, as determined by QASAP (quantitative analysis of self‐assembly process). This differs substantially from the self‐assembly process of a geometr...

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Published in:Chemistry : a European journal 2018-03, Vol.24 (16), p.3912-3912
Main Authors: Kai, Shumpei, Nakagawa, Masanori, Kojima, Tatsuo, Li, Xin, Yamashina, Masahiro, Yoshizawa, Michito, Hiraoka, Shuichi
Format: Article
Language:English
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molecular capsule
palladium
self-assembly
steric interactions
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container_end_page 3912
container_issue 16
container_start_page 3912
container_title Chemistry : a European journal
container_volume 24
creator Kai, Shumpei
Nakagawa, Masanori
Kojima, Tatsuo
Li, Xin
Yamashina, Masahiro
Yoshizawa, Michito
Hiraoka, Shuichi
description The self‐assembly of a Pd2L4 capsule consisting of Pd(II) ions and ditopic ligands comprising an anthracene panel takes place mainly through three pathways, as determined by QASAP (quantitative analysis of self‐assembly process). This differs substantially from the self‐assembly process of a geometrically similar Pd2L4 cage without anthracene panels, indicating that the interactions between the neighboring panels have a significant influence on the self‐assembly process. More information can be found in the Communication by S. Hiraoka et al. on page 3965.
doi_str_mv 10.1002/chem.201800146
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subjects molecular capsule
palladium
self-assembly
steric interactions
title Cover Feature: Self‐Assembly Process of a Pd2L4 Capsule: Steric Interactions between Neighboring Components Favor the Formation of Large Intermediates (Chem. Eur. J. 16/2018)
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