Cover Feature: DOTP versus DOTA as Ligands for Lanthanide Cations: Novel Structurally Characterized CeIV and CeIII Cyclen‐Based Complexes and Clusters in Aqueous Solutions (Chem. Eur. J. 61/2022)

A group of researchers from NRCN, Ben Gurion University and the CEA shows that cyclen‐derived, hard‐bonding ligands facilitate the formation of tetravalent cerium cations bearing oxo/hydroxo clusters in aqueous solutions. The clusters eventually decompose to form the thermodynamically favoured “in‐c...

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Bibliographic Details
Published in:Chemistry : a European journal 2022-11, Vol.28 (61), p.n/a
Main Authors: Dovrat, Gev, Pevzner, Svetlana, Maimon, Eric, Vainer, Radion, Iliashevsky, Olga, Ben‐Eliyahu, Yeshayahu, Moisy, Philippe, Bettelheim, Armand, Zilbermann, Israel
Format: Article
Language:English
Subjects:
cerium
cluster compounds
coordination chemistry
macrocyclic ligands
redox chemistry
structure
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Summary:A group of researchers from NRCN, Ben Gurion University and the CEA shows that cyclen‐derived, hard‐bonding ligands facilitate the formation of tetravalent cerium cations bearing oxo/hydroxo clusters in aqueous solutions. The clusters eventually decompose to form the thermodynamically favoured “in‐cage” cerric macrocyclic complex. More information can be found in the Research Article by S. Pevzner, E. Maimon, Y. Ben‐Eliyahu, P. Moisy, A. Bettelheim, I. Zilbermann and co‐workers (DOI: 10.1002/chem.202201868).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202203208