Synthesis of N3S, N3O, N2S2, N2O2, N2SO and N2OS Porphyrins with One meso-Unsubstituted Carbon

A simple straightforward synthesis of N3S, N2S2, N2O2, N2SO and N2OS porphyrins and an improved method for the synthesis of an N3O porphyrin with one meso‐unsubstituted carbon atom are reported from readily available precursors. The reactivity of the meso‐unsubstituted carbon atom was demonstrated b...

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Published in:European journal of organic chemistry 2004-05, Vol.2004 (10), p.2223-2230
Main Authors: Punidha, Sokkalingam, Agarwal, Neeraj, Burai, Ritwik, Ravikanth, Mangalampalli
Format: Article
Language:English
Subjects:
Furan diols
Heck reaction
Porphyrins
Synthetic methods
Thiophenes
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container_title European journal of organic chemistry
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creator Punidha, Sokkalingam
Agarwal, Neeraj
Burai, Ritwik
Ravikanth, Mangalampalli
description A simple straightforward synthesis of N3S, N2S2, N2O2, N2SO and N2OS porphyrins and an improved method for the synthesis of an N3O porphyrin with one meso‐unsubstituted carbon atom are reported from readily available precursors. The reactivity of the meso‐unsubstituted carbon atom was demonstrated by carrying out bromination followed by Heck coupling reactions. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
doi_str_mv 10.1002/ejoc.200300697
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source Wiley-Blackwell Read & Publish Collection
subjects Furan diols
Heck reaction
Porphyrins
Synthetic methods
Thiophenes
title Synthesis of N3S, N3O, N2S2, N2O2, N2SO and N2OS Porphyrins with One meso-Unsubstituted Carbon
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