A multitechnique surface analytical study of a segmented block copolymer poly(ether-urethane) modified through an H2O radio frequency glow discharge

• Published in: Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1991-03, Vol.29 (4), p.535-545
• Main Authors: Vargo, Terrence G., Hook, Daniel J., Gardella Jr, Joseph A., Eberhardt, Mary A., Meyer, Anne E., Baier, Robert E.
• Format: Article
• Language: English
• ISSN: 0887-624X; 1099-0518
• DOI: 10.1002/pola.1991.080290410

Recent work in our laboratories has fully characterized the surface region of a segmented poly(ether‐urethane) (PEU) extending from the air/polymer interfacial region through bulk depths in the micron range. This characterization utilized energy and angle dependent Electron Spectroscopy for Chemical Analysis (ESCA), Attenuated Total Reflectance–Fourier Transform Infrared Spectroscopy (ATR–FTIR), and Comprehensive Wettability Profiling (contact angle using a homologous series of liquids) as defined by Zisman. In this study this same multi‐analytical‐technique approach is used to elucidate changes in these PEU surfaces induced through an H2O Radio Frequency Glow Discharge (RFGD) plasma. This investigation reports both qualitative and quantitative changes due to the modification treatments as well as the permanency of the changes effected on these surfaces through the plasma treatment. From our analyses, the amount of surface residing polyurethane (hard segment) is observed to increase due to a proposed plasma etching mechanism. Further, the addition of oxygen containing functionality is detected at the modified surfaces unique with respect to the unmodified PEU. These surface modifications which show large increases in wettability, are finally observed to be semi‐permanent over a time period of 6 months.