Temperature Sensing Properties base on Up‐Conversion Luminescence for NaYF4: Er3+, Yb3+ Phosphor

• Published in: ChemistrySelect (Weinheim) 2019-04, Vol.4 (14), p.4316-4323
• Main Authors: Cui, Yanwen, Meng, Qingyu, Lü, Shuchen, Sun, Wenjun
• Format: Article
• Language: English
• Subjects: Er3; NaYF4; Temperature sensing; Up-conversion
• ISSN: 2365-6549; 2365-6549
• DOI: 10.1002/slct.201900719

EDTA was used as chelating agent to synthesize Er3+, Yb3+ co‐doped NaYF4 phosphor by hydrothermal process. The crystallographic structures were characterized by X‐ray Diffraction (XRD). The morphologies were analyzed by field emission scanning electron microscopy (FE ‐ SEM). It can be known that with the increase of the EDTA/Re3+, the crystalline phase of samples change from α phase to the β phase. The temperature‐dependent up‐conversion emission spectra of the samples have been tested by the 980 nm laser excitation. Temperature sensing properties of samples were studied based on the fluorescence intensity ratio for two thermally coupled levels 2H11/2 and 4S3/2 of Er3+. The results show that the optical temperature sensing sensitivity increased gradually along with the EDTA/Re3+ increasing, no matter the samples are α phase or β phase. And the sensitivity maximum of α phase samples is 0.00419 K−1 (at 486 K, EDTA/Re3+=3), the sensitivity maximum of β phase samples is 0.00466 K−1 (at 550 K, EDTA/Re3+=8). But the relative sensitivity has nothing to do with the amount of EDTA, only related to the crystalline phase. The relative sensitivity maximum of α phase samples is about 0.0105 K−1 (at 303 k), the maximum relative sensitivity of β phase samples is about 0.0120 K−1 (at 303 k). So, temperature sensing properties of β phase are better than that of α phase. NaYF4: Er3+, Yb3+ phosphors by using EDTA as chelating agent were synthesized via hydrothermal process. The crystalline phase of sample changes from α phase to the β phase with the increase of the EDTA/Re3+. Moreover, the morphology and size of sample are closely related to the amount of EDTA. And, the optical temperature sensing sensitivity increases gradually along with the EDTA/Re3+ increasing.