NiII-CdII Heterometallic Coordination Compounds Constructed from Metal-Containing N, N′-Rodlike Building Block [Ni(4′-(3-pyridyl)-2,2′:6′,2″-terpyridine)2]2+ Cation

Based on the use of [Ni(3‐pytpy)2][BF4]2 (3‐pytpy=4′‐(3‐pyridyl)‐2,2′:6′,2″‐terpyridine) (1) as expanded 3, 3′‐N, N′‐rodlike building blocks and CdII atoms as metal “nodes”, two novel NiII‐CdII heterometallic compounds [Ni(3‐pytpy)2Cd2Cl6] (2) and [Ni(3‐pytpy)2Cd(NCS‐κN)4]·CH3OH (3) have been synthe...

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Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2008-06, Vol.634 (6-7), p.1215-1220
Main Authors: Gou, Lei, Xu, Li-Feng, Hu, Huai-Ming, Wang, Bao-Cheng, Wu, Qing-Ran, Chen, Xiao-Li, Tang, Zong-Xun
Format: Article
Language:English
Subjects:
Cadmium
Metalloligand
Nickel
Terpyridine
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container_end_page 1220
container_issue 6-7
container_start_page 1215
container_title Zeitschrift für anorganische und allgemeine Chemie (1950)
container_volume 634
creator Gou, Lei
Xu, Li-Feng
Hu, Huai-Ming
Wang, Bao-Cheng
Wu, Qing-Ran
Chen, Xiao-Li
Tang, Zong-Xun
description Based on the use of [Ni(3‐pytpy)2][BF4]2 (3‐pytpy=4′‐(3‐pyridyl)‐2,2′:6′,2″‐terpyridine) (1) as expanded 3, 3′‐N, N′‐rodlike building blocks and CdII atoms as metal “nodes”, two novel NiII‐CdII heterometallic compounds [Ni(3‐pytpy)2Cd2Cl6] (2) and [Ni(3‐pytpy)2Cd(NCS‐κN)4]·CH3OH (3) have been synthesized under different conditions. In the precursory complex 1, NiII atom is coordinated by the tpy domains of two 3‐pytpy ligands, while the pyridyl tails remain uncoordinated. In compound 2, [Ni(3‐pytpy)2]2+ adopting cis‐conformation bridges two four‐coordinated CdII into trinuclear structure. In compound 3, [Ni(3‐pytpy)2]2+ adopting trans‐conformation connects six‐coordinated CdII into 1D chain and the chains were packed into double‐chains through face‐to‐face π‐π stacking interactions.
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In compound 3, [Ni(3‐pytpy)2]2+ adopting trans‐conformation connects six‐coordinated CdII into 1D chain and the chains were packed into double‐chains through face‐to‐face π‐π stacking interactions.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/zaac.200700492</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record>
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subjects Cadmium
Metalloligand
Nickel
Terpyridine
title NiII-CdII Heterometallic Coordination Compounds Constructed from Metal-Containing N, N′-Rodlike Building Block [Ni(4′-(3-pyridyl)-2,2′:6′,2″-terpyridine)2]2+ Cation
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