Di­cyclo­hexyl­ammonium 2,4-di­chloro­phenoxy­acetate and (2,4-di­chloro­phenoxy­acetato-O,O′)bis­(tri­phenylphosphine-P)silver(I)

The monoclinic cell of di­cyclo­hexyl­ammonium 2,4‐di­chloro­phenoxy­acetate contains four C12H24N+·C5H8Cl2O3− ion pairs. The ammonium N atom is hydrogen bonded to the oxy­gen ends of two carboxyl groups to form a 12‐membered O—C—O⋯HNH⋯O—C—O⋯HNH ring. In (2,4‐di­chloro­phenoxy­lacetato)­bis­(tri­phe...

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Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-07, Vol.56 (7), p.e292-e294
Main Authors: Subramanian, Ramis Rao, Anandan, Shanmuga S., Kwek, Kuan Hiang, Low, Kum Sang, Shanmuga Sundara Raj, S., Fun, Hoong-Kun, Razak, Ibrahim Abdul, Hanna, John V., Ng, Seik Weng
Format: Article
Language:English
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Summary:The monoclinic cell of di­cyclo­hexyl­ammonium 2,4‐di­chloro­phenoxy­acetate contains four C12H24N+·C5H8Cl2O3− ion pairs. The ammonium N atom is hydrogen bonded to the oxy­gen ends of two carboxyl groups to form a 12‐membered O—C—O⋯HNH⋯O—C—O⋯HNH ring. In (2,4‐di­chloro­phenoxy­lacetato)­bis­(tri­phenyl­phosphine)silver(I), [Ag(C8H5Cl2O3)(C18H15P)2], the carboxyl CO2 unit chelates to the Ag atom in an anisobidentate manner [Ag—O = 2.436 (2) and 2.517 (2) Å]; the Ag atom shows distorted tetrahedral geometry.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270100007903