A one-dimensional coordination polymer with metal-metal inter­actions: catena-poly­[[tri­aqua­barium(II)]-μ-aqua-κ2O:O-di-μ-thio­salicyl­ato-κ4O:O]

In the title compound, [Ba(C7H5O2S)2(H2O)4]n, the BaII atom lies on a mirror plane and is nine‐coordinated by four bridging carboxylate O atoms of the thio­salicyl­ate ligands, two bridging water mol­ecules and three terminal water mol­ecules. There is an intramolecular S—H⋯O hydrogen bond between t...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-05, Vol.59 (5), p.m196-m198
Main Authors: Lee, Bo-Hyung, Kim, Chong-Hyeak, Lee, Sueg-Geun
Format: Article
Language:English
Online Access:Get full text
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Summary:In the title compound, [Ba(C7H5O2S)2(H2O)4]n, the BaII atom lies on a mirror plane and is nine‐coordinated by four bridging carboxylate O atoms of the thio­salicyl­ate ligands, two bridging water mol­ecules and three terminal water mol­ecules. There is an intramolecular S—H⋯O hydrogen bond between the S and O atoms in the thio­salicyl­ate ligand. A one‐dimensional coordination polymer is formed via weak metal–metal interactions along polymeric zigzag chains.
ISSN:0108-2701
1600-5759
DOI:10.1107/S010827010300667X