A novel thio­cyanate-bridged one-dimensional chain complex: [Cu(NCS)2(Hambi)] (Hambi is 2-amino­methyl-1H-benz­imidazole)

Using 2‐amino­methyl‐1H‐benz­imidazole as the ligand, a new thio­cyanate‐bridged copper(II) complex, namely bis(2‐aminomethyl‐1H‐benz­imidazole‐κ2N2,N3)­di­thio­cyanato­copper(II),[Cu(NCS)2(C8H9N3)], has been synthesized and structurally characterized. The Cu atom is five‐coordinated and exhibits a...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-06, Vol.60 (6), p.m261-m262
Main Authors: Jiang, Yun-Bo, Kou, Hui-Zhong, Gao, Fei, Wang, Ru-Ji
Format: Article
Language:English
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Summary:Using 2‐amino­methyl‐1H‐benz­imidazole as the ligand, a new thio­cyanate‐bridged copper(II) complex, namely bis(2‐aminomethyl‐1H‐benz­imidazole‐κ2N2,N3)­di­thio­cyanato­copper(II),[Cu(NCS)2(C8H9N3)], has been synthesized and structurally characterized. The Cu atom is five‐coordinated and exhibits a distorted square‐pyramidal geometry. The thio­cyanate ions (NCS−) act as either bridging or terminal ligands. The bridging NCS− ligands connect neighboring Cu atoms, constructing chains, while the terminal NCS− ligands form hydrogen bonds with amine H atoms, leading to a complicated network.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270104009102