Sn4.4Mo24O38

The single‐crystal structure of tetratin tetracosa­molybdenum octatriaconta­oxide, Sn4.4Mo24O38, contains infinite chains of centrosymmetric dioctahedral Mo10 and centrosymmetric trioctahedral Mo14 clusters. These clusters, as well as the O atoms, the arrangement of which derives from a closest‐pack...

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Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2000-03, Vol.56 (3), p.269-271
Main Authors: Barrier, N., Tortelier, J., Gougeon, P.
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container_title Acta crystallographica. Section C, Crystal structure communications
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Tortelier, J.
Gougeon, P.
description The single‐crystal structure of tetratin tetracosa­molybdenum octatriaconta­oxide, Sn4.4Mo24O38, contains infinite chains of centrosymmetric dioctahedral Mo10 and centrosymmetric trioctahedral Mo14 clusters. These clusters, as well as the O atoms, the arrangement of which derives from a closest‐packing with the layer sequence …ABAC…, form sheets parallel to the ac plane of the monoclinic unit cell. The Mo—Mo distances range from 2.6225 (7) to 2.8212 (9) Å and from 2.6270 (7) to 2.8365 (7) Å in the Mo10 and Mo14 clusters, respectively. The Mo—O distances vary between 1.949 (4) and 2.151 (4) Å in the Mo10 cluster and between 1.938 (4) and 2.140 (4) Å in the Mo14 cluster. The three crystallographically independent Sn2+ ions are off the centre of distorted oxy­gen octahedra.
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These clusters, as well as the O atoms, the arrangement of which derives from a closest‐packing with the layer sequence …ABAC…, form sheets parallel to the ac plane of the monoclinic unit cell. The Mo—Mo distances range from 2.6225 (7) to 2.8212 (9) Å and from 2.6270 (7) to 2.8365 (7) Å in the Mo10 and Mo14 clusters, respectively. The Mo—O distances vary between 1.949 (4) and 2.151 (4) Å in the Mo10 cluster and between 1.938 (4) and 2.140 (4) Å in the Mo14 cluster. The three crystallographically independent Sn2+ ions are off the centre of distorted oxy­gen octahedra.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270199015127</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: Munksgaard International Publishers</publisher><ispartof>Acta crystallographica. 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These clusters, as well as the O atoms, the arrangement of which derives from a closest‐packing with the layer sequence …ABAC…, form sheets parallel to the ac plane of the monoclinic unit cell. The Mo—Mo distances range from 2.6225 (7) to 2.8212 (9) Å and from 2.6270 (7) to 2.8365 (7) Å in the Mo10 and Mo14 clusters, respectively. The Mo—O distances vary between 1.949 (4) and 2.151 (4) Å in the Mo10 cluster and between 1.938 (4) and 2.140 (4) Å in the Mo14 cluster. 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Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barrier, N.</au><au>Tortelier, J.</au><au>Gougeon, P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sn4.4Mo24O38</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Cryst. C</addtitle><date>2000-03</date><risdate>2000</risdate><volume>56</volume><issue>3</issue><spage>269</spage><epage>271</epage><pages>269-271</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>The single‐crystal structure of tetratin tetracosa­molybdenum octatriaconta­oxide, Sn4.4Mo24O38, contains infinite chains of centrosymmetric dioctahedral Mo10 and centrosymmetric trioctahedral Mo14 clusters. These clusters, as well as the O atoms, the arrangement of which derives from a closest‐packing with the layer sequence …ABAC…, form sheets parallel to the ac plane of the monoclinic unit cell. The Mo—Mo distances range from 2.6225 (7) to 2.8212 (9) Å and from 2.6270 (7) to 2.8365 (7) Å in the Mo10 and Mo14 clusters, respectively. The Mo—O distances vary between 1.949 (4) and 2.151 (4) Å in the Mo10 cluster and between 1.938 (4) and 2.140 (4) Å in the Mo14 cluster. The three crystallographically independent Sn2+ ions are off the centre of distorted oxy­gen octahedra.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Munksgaard International Publishers</pub><doi>10.1107/S0108270199015127</doi><tpages>3</tpages></addata></record>
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title Sn4.4Mo24O38
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