Conformational dependence of triplet energies in rotationally‐hindered N‐ and S‐heterocyclic dimers: new design and measurement rules for high triplet energy OLED host materials

A series of four heterocyclic dimers has been synthesized, with twisted geometries imposed across the central linking bond by ortho‐alkoxy chains. These include two isomeric bicarbazoles, a bis(dibenzothiophene‐S,S‐dioxide) and a bis(thioxanthene‐S,S‐dioxide). Spectroscopic and electrochemical metho...

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Bibliographic Details
Main Authors: Iain Wright, Andrew Danos, Stephanie Montanaro, Andrei S Batsanov, Andrew P Monkman, Martin R Bryce
Format: Default Article
Published: 2021
Subjects:
Heterocycles
Photophysics
OLED
Triplet
Dihedral angle
Online Access:https://hdl.handle.net/2134/14034803.v1
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Summary:A series of four heterocyclic dimers has been synthesized, with twisted geometries imposed across the central linking bond by ortho‐alkoxy chains. These include two isomeric bicarbazoles, a bis(dibenzothiophene‐S,S‐dioxide) and a bis(thioxanthene‐S,S‐dioxide). Spectroscopic and electrochemical methods, supported by density functional theory, have given detailed insights into how para‐ vs. meta‐ vs. broken conjugation, and electron‐rich vs. electron‐poor heterocycles impact the HOMO‐LUMO gap and singlet and triplet energies. Crucially for applications as OLED hosts, the triplet energy (ET) of these molecules was found to vary significantly between dilute polymer films and neat films, related to conformational demands of the molecules in the solid state. One of the bicarbazole species shows a variation in ET of 0.24 eV in the different media – sufficiently large to “make‐or‐break” an OLED device – with similar discrepancies found between neat films and frozen solution measurements of other previously reported OLED hosts. From consolidated optical and optoelectronic investigations of different host/dopant combinations, we identify that only the lower ET values measured in neat films give a reliable indicator of host/guest compatibility. This work also provides new molecular design rules for obtaining very high ET materials and controlling their HOMO and LUMO energies.

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