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Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell

Experimental test and analytical modeling are conducted to investigate the operating behavior of an alkaline electrolyte membrane (AEM) fuel cell fed by H2/air (or O2) and explore the effect of various operating pressures on the water transfer mechanism. According to the experimental test, the cell...

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Main Authors: Sen Huo, Jiaxun Zhou, Tianyou Wang, Rui Chen, Kui Jiao
Format: Default Article
Published: 2018
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Online Access:https://hdl.handle.net/2134/28460
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author Sen Huo
Jiaxun Zhou
Tianyou Wang
Rui Chen
Kui Jiao
author_facet Sen Huo
Jiaxun Zhou
Tianyou Wang
Rui Chen
Kui Jiao
author_sort Sen Huo (7122869)
collection Figshare
description Experimental test and analytical modeling are conducted to investigate the operating behavior of an alkaline electrolyte membrane (AEM) fuel cell fed by H2/air (or O2) and explore the effect of various operating pressures on the water transfer mechanism. According to the experimental test, the cell performance is greatly improved through increasing the operating pressure gradient from anode to cathode which leads to significant liquid water permeation through the membrane. The high frequency resistance of the A901 alkaline membrane is observed to be relatively stable as the operating pressure varies based on the electrochemical impedance spectroscopy (EIS) method. Correspondingly, based on the modeling prediction, the averaged water content in the membrane electrode assembly (MEA) does not change too much which leads to the weak variation of membrane ohmic resistance. This reveals that the performance enhancement should give the credit to better electro-chemical reaction kinetics for both the anode and cathode, also prone by the EIS results. The reversion of water back diffusion direction across the membrane is also observed through analytical solution.
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institution Loughborough University
publishDate 2018
record_format Figshare
spelling rr-article-92267632018-02-14T00:00:00Z Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell Sen Huo (7122869) Jiaxun Zhou (7122872) Tianyou Wang (302431) Rui Chen (1257861) Kui Jiao (1609375) Other engineering not elsewhere classified Alkaline electrolyte membrane fuel cell Experimental test Analytical model Water transport Engineering not elsewhere classified Experimental test and analytical modeling are conducted to investigate the operating behavior of an alkaline electrolyte membrane (AEM) fuel cell fed by H2/air (or O2) and explore the effect of various operating pressures on the water transfer mechanism. According to the experimental test, the cell performance is greatly improved through increasing the operating pressure gradient from anode to cathode which leads to significant liquid water permeation through the membrane. The high frequency resistance of the A901 alkaline membrane is observed to be relatively stable as the operating pressure varies based on the electrochemical impedance spectroscopy (EIS) method. Correspondingly, based on the modeling prediction, the averaged water content in the membrane electrode assembly (MEA) does not change too much which leads to the weak variation of membrane ohmic resistance. This reveals that the performance enhancement should give the credit to better electro-chemical reaction kinetics for both the anode and cathode, also prone by the EIS results. The reversion of water back diffusion direction across the membrane is also observed through analytical solution. 2018-02-14T00:00:00Z Text Journal contribution 2134/28460 https://figshare.com/articles/journal_contribution/Experimental_and_analytical_analysis_of_polarization_and_water_transport_behaviors_of_hydrogen_alkaline_membrane_fuel_cell/9226763 CC BY-NC-ND 4.0
spellingShingle Other engineering not elsewhere classified
Alkaline electrolyte membrane fuel cell
Experimental test
Analytical model
Water transport
Engineering not elsewhere classified
Sen Huo
Jiaxun Zhou
Tianyou Wang
Rui Chen
Kui Jiao
Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell
title Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell
title_full Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell
title_fullStr Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell
title_full_unstemmed Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell
title_short Experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell
title_sort experimental and analytical analysis of polarization and water transport behaviors of hydrogen alkaline membrane fuel cell
topic Other engineering not elsewhere classified
Alkaline electrolyte membrane fuel cell
Experimental test
Analytical model
Water transport
Engineering not elsewhere classified
url https://hdl.handle.net/2134/28460