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Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column

A novel approach for the intensification of ozonation of water and wastewater is presented using a highly efficient and compact Multi-Orifice Oscillatory Baffled Column (MOBC) ozonation contactor. The MOBC uniquely yielded full (i.e. 100%) use of the ozone supplied with a very short (2.25 min) liqui...

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Main Authors: Marco S. Lucas, Nuno Reis, Gianluca Li-Puma
Format: Default Article
Published: 2016
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Online Access:https://hdl.handle.net/2134/21616
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author Marco S. Lucas
Nuno Reis
Gianluca Li-Puma
author_facet Marco S. Lucas
Nuno Reis
Gianluca Li-Puma
author_sort Marco S. Lucas (7128254)
collection Figshare
description A novel approach for the intensification of ozonation of water and wastewater is presented using a highly efficient and compact Multi-Orifice Oscillatory Baffled Column (MOBC) ozonation contactor. The MOBC uniquely yielded full (i.e. 100%) use of the ozone supplied with a very short (2.25 min) liquid contact time under continuous operation and reducing the need of further gas-liquid contacting equipment downstream from the MOBC. The increased performance of the MOBC ozonation reactor was benchmarked against a bubble column (BC) design and resulted in 20% increase on the rate of p-hydroxybenzoic acid (p-HBA) degradation, 75% increase in the rate of mineralization of p-HBA per mole of ozone consumed, and 3.2-fold increase in the rate of mineralization of p-HBA per mole of ozone supplied. This results from the very small size of bubbles (few hundreds of microns) and enhanced gas-liquid mass transfer and hold-up generated in the presence of small fluid pulsations and orifice baffles.
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institution Loughborough University
publishDate 2016
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spelling rr-article-92451292016-01-01T00:00:00Z Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column Marco S. Lucas (7128254) Nuno Reis (1254129) Gianluca Li-Puma (1252566) Chemical engineering not elsewhere classified Multi-orifice oscillatory baffled column Ozonation p-Hydroxybenzoic acid Process intensification Water and wastewater treatment Chemical Engineering not elsewhere classified A novel approach for the intensification of ozonation of water and wastewater is presented using a highly efficient and compact Multi-Orifice Oscillatory Baffled Column (MOBC) ozonation contactor. The MOBC uniquely yielded full (i.e. 100%) use of the ozone supplied with a very short (2.25 min) liquid contact time under continuous operation and reducing the need of further gas-liquid contacting equipment downstream from the MOBC. The increased performance of the MOBC ozonation reactor was benchmarked against a bubble column (BC) design and resulted in 20% increase on the rate of p-hydroxybenzoic acid (p-HBA) degradation, 75% increase in the rate of mineralization of p-HBA per mole of ozone consumed, and 3.2-fold increase in the rate of mineralization of p-HBA per mole of ozone supplied. This results from the very small size of bubbles (few hundreds of microns) and enhanced gas-liquid mass transfer and hold-up generated in the presence of small fluid pulsations and orifice baffles. 2016-01-01T00:00:00Z Text Journal contribution 2134/21616 https://figshare.com/articles/journal_contribution/Intensification_of_ozonation_processes_in_a_novel_compact_multi-orifice_oscillatory_baffled_column/9245129 CC BY-NC-ND 4.0
spellingShingle Chemical engineering not elsewhere classified
Multi-orifice oscillatory baffled column
Ozonation
p-Hydroxybenzoic acid
Process intensification
Water and wastewater treatment
Chemical Engineering not elsewhere classified
Marco S. Lucas
Nuno Reis
Gianluca Li-Puma
Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column
title Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column
title_full Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column
title_fullStr Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column
title_full_unstemmed Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column
title_short Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column
title_sort intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column
topic Chemical engineering not elsewhere classified
Multi-orifice oscillatory baffled column
Ozonation
p-Hydroxybenzoic acid
Process intensification
Water and wastewater treatment
Chemical Engineering not elsewhere classified
url https://hdl.handle.net/2134/21616