The first use of the free selenimide Ph(2)Se=NH as a synthon; the synthesis and X-ray crystal structure of [Ph(2)SeNSePh(2)][BPh(4)]

Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2Se[double bond, length as m-dash]NH and Ph2Se[double bond...

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Bibliographic Details

Main Authors:	Mark Elsegood, Paul Kelly, Gillian Reid, Paul M. Staniland
Format:	Default Article
Published:	2008
Subjects:	Inorganic chemistry not elsewhere classified Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified Inorganic Chemistry
Online Access:	https://hdl.handle.net/2134/15622
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