An extensive family of heterometallic titanium(IV)-metal(III) rings with structure control through templates

A family of heterometallic [Cat][TixMO(x+1)(O2CtBu)2x+2] rings is reported where Cat=a secondary or tertiary alkyl ammonium ion, x=7, 8 or 9, and M=FeIII, GaIII, CrIII, InIII and AlIII. The structures are regular polygons with eight, nine or ten vertices with each edge bridged by an oxide and two pi...

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Bibliographic Details
Main Authors: Grigore A. Timco, Antonio Fernandez-Mato, Andreas K. Kostopoulos, Christopher A. Muryn, Robin G. Pritchard, Ilya Strashnov, Inigo J. Vitorica-Yrezabal, George F. Whitehead, Richard E. Winpenny
Format: Default Article
Published: 2017
Subjects:
Other chemical sciences not elsewhere classified
Carboxylates
Heterometallic rings
Template synthesis
Titanium
Chemical Sciences not elsewhere classified
Online Access:https://hdl.handle.net/2134/37377
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https://hdl.handle.net/2134/37377

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