Vanadium(V) phenolate complexes for ring opening homo- and co-polymerisation of [epsilon]-caprolactone, L-lactide and rac-lactide

The vanadyl complexes [VO(OtBu)L1] (1) and {[VO(OiPr)]2(m-p-L2p)} (2) {[VO(OR)]2(m-p-L2m)} (R ¼ iPr 3, tBu 4) have been prepared from [VO(OR)3] (R ¼ nPr, iPr or tBu) and the respective phenol, namely 2,20- ethylidenebis(4,6-di-tert-butylphenol) (L1H2) or a,a,a 0 ,a 0-tetra(3,5-di-tert-butyl-2-hydrox...

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Bibliographic Details
Main Authors: Feijie Ge, Yi Dan, Yahya Al-Khafaji, Timothy J. Prior, Long Jiang, Mark Elsegood, Carl Redshaw
Format: Default Article
Published: 2015
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Online Access:https://hdl.handle.net/2134/20131
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