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Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes
The syntheses and electrochemical properties of new mono- and di-ferrocenyl bipyridyl ligands containing trans conjugated olefinic linkages between the ferrocene redox centres and the 4,4′-substituted 2,2′-bipyridine (bipy) moieties are described. The corresponding ruthenium(II) complexes have been...
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| Format: | Default Article |
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1990
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| Online Access: | https://hdl.handle.net/2134/11485 |
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| _version_ | 1818174235568242688 |
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| author | Paul D. Beer Oldrich Kocian Roger J. Mortimer |
| author_facet | Paul D. Beer Oldrich Kocian Roger J. Mortimer |
| author_sort | Paul D. Beer (818121) |
| collection | Figshare |
| description | The syntheses and electrochemical properties of new mono- and di-ferrocenyl bipyridyl ligands containing trans conjugated olefinic linkages between the ferrocene redox centres and the 4,4′-substituted 2,2′-bipyridine (bipy) moieties are described. The corresponding ruthenium(II) complexes have been prepared and one complex, [RuL4(bipy)2][PF6]2[L4= 4,4′-bis(ferrocenylvinyl)-2,2′-bipyridine], undergoes electrochemical polymerisation to produce an electrochromic polymer film. |
| format | Default Article |
| id | rr-article-9394733 |
| institution | Loughborough University |
| publishDate | 1990 |
| record_format | Figshare |
| spelling | rr-article-93947331990-01-01T00:00:00Z Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes Paul D. Beer (818121) Oldrich Kocian (2997840) Roger J. Mortimer (1942423) Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified The syntheses and electrochemical properties of new mono- and di-ferrocenyl bipyridyl ligands containing trans conjugated olefinic linkages between the ferrocene redox centres and the 4,4′-substituted 2,2′-bipyridine (bipy) moieties are described. The corresponding ruthenium(II) complexes have been prepared and one complex, [RuL4(bipy)2][PF6]2[L4= 4,4′-bis(ferrocenylvinyl)-2,2′-bipyridine], undergoes electrochemical polymerisation to produce an electrochromic polymer film. 1990-01-01T00:00:00Z Text Journal contribution 2134/11485 https://figshare.com/articles/journal_contribution/Novel_mono-_and_di-ferrocenyl_bipyridyl_ligands_syntheses_electrochemistry_and_electropolymerisation_studies_of_their_ruthenium_II_complexes/9394733 CC BY-NC-ND 4.0 |
| spellingShingle | Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified Paul D. Beer Oldrich Kocian Roger J. Mortimer Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes |
| title | Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes |
| title_full | Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes |
| title_fullStr | Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes |
| title_full_unstemmed | Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes |
| title_short | Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes |
| title_sort | novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(ii) complexes |
| topic | Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified |
| url | https://hdl.handle.net/2134/11485 |