Loading…
Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry
The complexation of triacetone triperoxide (TATP) with a range of alkali metals has been studied by electrospray ionisation-mass spectrometry yield [M+Cat]+ ions for all of the alkali metals. The formation of [2TATP+Li+LiX]+ (X = Br, Cl) sandwich complexes was also observed. Collision cross-sections...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Default Article |
| Published: |
2015
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/2134/19297 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1818172567570087936 |
|---|---|
| author | Alexander R. Hill Mark Edgar Maria Chatzigeorgiou Jim Reynolds Paul Kelly Colin Creaser |
| author_facet | Alexander R. Hill Mark Edgar Maria Chatzigeorgiou Jim Reynolds Paul Kelly Colin Creaser |
| author_sort | Alexander R. Hill (7165364) |
| collection | Figshare |
| description | The complexation of triacetone triperoxide (TATP) with a range of alkali metals has been studied by electrospray ionisation-mass spectrometry yield [M+Cat]+ ions for all of the alkali metals. The formation of [2TATP+Li+LiX]+ (X = Br, Cl) sandwich complexes was also observed. Collision cross-sections for the lithium-containing complexes of TATP were measured by travelling wave ion mobility spectrometry mass spectrometry, and compared well with computationally determined structures. Extractive electrospray ionisation (EESI) using a lithium doped electrospray is demonstrated for the detection of TATP vapours desorbed from a metal surface. The limit of detection for EESI was shown to be 20 ng using the [TATP+Li]+ ion. |
| format | Default Article |
| id | rr-article-9394916 |
| institution | Loughborough University |
| publishDate | 2015 |
| record_format | Figshare |
| spelling | rr-article-93949162015-01-01T00:00:00Z Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry Alexander R. Hill (7165364) Mark Edgar (1249263) Maria Chatzigeorgiou (7165367) Jim Reynolds (1248186) Paul Kelly (1248462) Colin Creaser (1249998) Other chemical sciences not elsewhere classified Triacetone triperoxide Ion mobility-mass spectrometry Collision cross-section Extractive electrospray ionisation Chemical Sciences not elsewhere classified The complexation of triacetone triperoxide (TATP) with a range of alkali metals has been studied by electrospray ionisation-mass spectrometry yield [M+Cat]+ ions for all of the alkali metals. The formation of [2TATP+Li+LiX]+ (X = Br, Cl) sandwich complexes was also observed. Collision cross-sections for the lithium-containing complexes of TATP were measured by travelling wave ion mobility spectrometry mass spectrometry, and compared well with computationally determined structures. Extractive electrospray ionisation (EESI) using a lithium doped electrospray is demonstrated for the detection of TATP vapours desorbed from a metal surface. The limit of detection for EESI was shown to be 20 ng using the [TATP+Li]+ ion. 2015-01-01T00:00:00Z Text Journal contribution 2134/19297 https://figshare.com/articles/journal_contribution/Analysis_of_triacetone_triperoxide_complexes_with_alkali_metal_ions_by_electrospray_and_extractive_electrospray_ionisation_combined_with_ion_mobility_spectrometry_and_mass_spectrometry/9394916 CC BY-NC-ND 4.0 |
| spellingShingle | Other chemical sciences not elsewhere classified Triacetone triperoxide Ion mobility-mass spectrometry Collision cross-section Extractive electrospray ionisation Chemical Sciences not elsewhere classified Alexander R. Hill Mark Edgar Maria Chatzigeorgiou Jim Reynolds Paul Kelly Colin Creaser Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry |
| title | Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry |
| title_full | Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry |
| title_fullStr | Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry |
| title_full_unstemmed | Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry |
| title_short | Analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry |
| title_sort | analysis of triacetone triperoxide complexes with alkali metal ions by electrospray and extractive electrospray ionisation combined with ion mobility spectrometry and mass spectrometry |
| topic | Other chemical sciences not elsewhere classified Triacetone triperoxide Ion mobility-mass spectrometry Collision cross-section Extractive electrospray ionisation Chemical Sciences not elsewhere classified |
| url | https://hdl.handle.net/2134/19297 |