Lewis base-catalyzed reactions of SiX 3-based reagents with C=O, C=N (n → σ*)

Nucleophilic addition to carbonyl and heterocarbonyl compounds is the cornerstone of organic synthesis, highlighted by the classical examples of Grignard reactions, aldol condensation, and H4 reductions. However, when less reactive nucleophiles are employed, such as allyl-silane, activation is requi...

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Bibliographic Details
Main Authors: Andrei Malkov, Pavel Kocovsky
Format: Default Book chapter
Published: 2016
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Online Access:https://hdl.handle.net/2134/22507
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