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Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative
Triply fused 1,3-diazepine derivatives have been obtained by acidic reduction of rotationally locked and sterically hindered nitro groups in the presence of an aldehyde or ketone. The nitro groups are sited on adjacent rings of a dicyanodibenzothiophene-5,5-dioxide, which also displays fully reversi...
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| Format: | Default Article |
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2018
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| Online Access: | https://hdl.handle.net/2134/35233 |
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| _version_ | 1818169268628357120 |
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| author | Stephanie Montanaro Iain Wright Andrei S. Batsanov Martin R. Bryce |
| author_facet | Stephanie Montanaro Iain Wright Andrei S. Batsanov Martin R. Bryce |
| author_sort | Stephanie Montanaro (5783033) |
| collection | Figshare |
| description | Triply fused 1,3-diazepine derivatives have been obtained by acidic reduction of rotationally locked and sterically hindered nitro groups in the presence of an aldehyde or ketone. The nitro groups are sited on adjacent rings of a dicyanodibenzothiophene-5,5-dioxide, which also displays fully reversible two-electron-accepting behavior. The synthesis, crystallographically determined molecular structures, and aspects of the electronic properties of these new molecules are presented. |
| format | Default Article |
| id | rr-article-9395828 |
| institution | Loughborough University |
| publishDate | 2018 |
| record_format | Figshare |
| spelling | rr-article-93958282018-09-24T00:00:00Z Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative Stephanie Montanaro (5783033) Iain Wright (3281406) Andrei S. Batsanov (1470295) Martin R. Bryce (1448968) Organic chemistry not elsewhere classified Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified Organic Chemistry Triply fused 1,3-diazepine derivatives have been obtained by acidic reduction of rotationally locked and sterically hindered nitro groups in the presence of an aldehyde or ketone. The nitro groups are sited on adjacent rings of a dicyanodibenzothiophene-5,5-dioxide, which also displays fully reversible two-electron-accepting behavior. The synthesis, crystallographically determined molecular structures, and aspects of the electronic properties of these new molecules are presented. 2018-09-24T00:00:00Z Text Journal contribution 2134/35233 https://figshare.com/articles/journal_contribution/Synthesis_of_Tetracyclic_2_3-Dihydro-1_3-diazepines_from_a_Dinitrodibenzothiophene_derivative/9395828 CC BY-NC-ND 4.0 |
| spellingShingle | Organic chemistry not elsewhere classified Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified Organic Chemistry Stephanie Montanaro Iain Wright Andrei S. Batsanov Martin R. Bryce Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative |
| title | Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative |
| title_full | Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative |
| title_fullStr | Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative |
| title_full_unstemmed | Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative |
| title_short | Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative |
| title_sort | synthesis of tetracyclic 2,3-dihydro-1,3-diazepines from a dinitrodibenzothiophene derivative |
| topic | Organic chemistry not elsewhere classified Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified Organic Chemistry |
| url | https://hdl.handle.net/2134/35233 |