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Some studies in the chemistry of reactive intermediates
A number of reactions of tetrahalogenobenzynes have been investigated. The reactions of tetrafluorobenzyne with 2-methyl- and 2,5-dimethylfuran gave the expected Diels–Alder adducts (dihydro-tetrafluoroepoxinaphthalene derivatives) which on treatment with butadiene afforded 9-methyl- and 9,10-dimeth...
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| Format: | Default Thesis |
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1975
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| Online Access: | https://hdl.handle.net/2134/34894 |
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| _version_ | 1818169318394822656 |
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| author | Ram P. Sharma |
| author_facet | Ram P. Sharma |
| author_sort | Ram P. Sharma (4524451) |
| collection | Figshare |
| description | A number of reactions of tetrahalogenobenzynes have been investigated. The reactions of tetrafluorobenzyne with 2-methyl- and 2,5-dimethylfuran gave the expected Diels–Alder adducts (dihydro-tetrafluoroepoxinaphthalene derivatives) which on treatment with butadiene afforded 9-methyl- and 9,10-dimethyltetrahydrotetrafluoroanthracenes. Further reactions with tetrafluorobenzyne followed by dehydrogenation gave 9-methyl- and 9,10-dimethyloctafluorotriptycenes which were used to study new examples of long-range 19F–1H spin–spin coupling 1H NMR spectroscopy. [Continues.] |
| format | Default Thesis |
| id | rr-article-9396245 |
| institution | Loughborough University |
| publishDate | 1975 |
| record_format | Figshare |
| spelling | rr-article-93962451975-01-01T00:00:00Z Some studies in the chemistry of reactive intermediates Ram P. Sharma (4524451) Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified A number of reactions of tetrahalogenobenzynes have been investigated. The reactions of tetrafluorobenzyne with 2-methyl- and 2,5-dimethylfuran gave the expected Diels–Alder adducts (dihydro-tetrafluoroepoxinaphthalene derivatives) which on treatment with butadiene afforded 9-methyl- and 9,10-dimethyltetrahydrotetrafluoroanthracenes. Further reactions with tetrafluorobenzyne followed by dehydrogenation gave 9-methyl- and 9,10-dimethyloctafluorotriptycenes which were used to study new examples of long-range 19F–1H spin–spin coupling 1H NMR spectroscopy. [Continues.] 1975-01-01T00:00:00Z Text Thesis 2134/34894 https://figshare.com/articles/thesis/Some_studies_in_the_chemistry_of_reactive_intermediates/9396245 CC BY-NC-ND 4.0 |
| spellingShingle | Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified Ram P. Sharma Some studies in the chemistry of reactive intermediates |
| title | Some studies in the chemistry of reactive intermediates |
| title_full | Some studies in the chemistry of reactive intermediates |
| title_fullStr | Some studies in the chemistry of reactive intermediates |
| title_full_unstemmed | Some studies in the chemistry of reactive intermediates |
| title_short | Some studies in the chemistry of reactive intermediates |
| title_sort | some studies in the chemistry of reactive intermediates |
| topic | Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified |
| url | https://hdl.handle.net/2134/34894 |