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Retention-modification in HPLC using metal ions

The effects of transition metal ions as components of the mobile phase on the retentions in HPLC of 2-aminophenol and selected α-diketones were studied on both ODS-silica and porous polymer columns. The compounds were used as model compounds in an investigation which set out to derive a detailed und...

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Main Author: Simon J. Bale
Format: Default Thesis
Published: 1988
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Online Access:https://hdl.handle.net/2134/27578
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author Simon J. Bale
author_facet Simon J. Bale
author_sort Simon J. Bale (7166390)
collection Figshare
description The effects of transition metal ions as components of the mobile phase on the retentions in HPLC of 2-aminophenol and selected α-diketones were studied on both ODS-silica and porous polymer columns. The compounds were used as model compounds in an investigation which set out to derive a detailed understanding of the mechanisms Involved when metal ions are used to selectively modify the retention of compounds capable of interaction. This technique, which has parallels with ion-pair chromatography, provides another method by which the conditions of a separation may be altered and the selectivity adjusted to give better resolution. [Continues.]
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Thesis
id rr-article-9397430
institution Loughborough University
publishDate 1988
record_format Figshare
spelling rr-article-93974301988-01-01T00:00:00Z Retention-modification in HPLC using metal ions Simon J. Bale (7166390) Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified The effects of transition metal ions as components of the mobile phase on the retentions in HPLC of 2-aminophenol and selected α-diketones were studied on both ODS-silica and porous polymer columns. The compounds were used as model compounds in an investigation which set out to derive a detailed understanding of the mechanisms Involved when metal ions are used to selectively modify the retention of compounds capable of interaction. This technique, which has parallels with ion-pair chromatography, provides another method by which the conditions of a separation may be altered and the selectivity adjusted to give better resolution. [Continues.] 1988-01-01T00:00:00Z Text Thesis 2134/27578 https://figshare.com/articles/thesis/Retention-modification_in_HPLC_using_metal_ions/9397430 CC BY-NC-ND 2.5
spellingShingle Other chemical sciences not elsewhere classified
untagged
Chemical Sciences not elsewhere classified
Simon J. Bale
Retention-modification in HPLC using metal ions
title Retention-modification in HPLC using metal ions
title_full Retention-modification in HPLC using metal ions
title_fullStr Retention-modification in HPLC using metal ions
title_full_unstemmed Retention-modification in HPLC using metal ions
title_short Retention-modification in HPLC using metal ions
title_sort retention-modification in hplc using metal ions
topic Other chemical sciences not elsewhere classified
untagged
Chemical Sciences not elsewhere classified
url https://hdl.handle.net/2134/27578