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Retention-modification in HPLC using metal ions
The effects of transition metal ions as components of the mobile phase on the retentions in HPLC of 2-aminophenol and selected α-diketones were studied on both ODS-silica and porous polymer columns. The compounds were used as model compounds in an investigation which set out to derive a detailed und...
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1988
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Online Access: | https://hdl.handle.net/2134/27578 |
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_version_ | 1818170787598696448 |
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author | Simon J. Bale |
author_facet | Simon J. Bale |
author_sort | Simon J. Bale (7166390) |
collection | Figshare |
description | The effects of transition metal ions as components of the mobile phase on the retentions in HPLC of 2-aminophenol and selected α-diketones were studied on both ODS-silica and porous polymer columns. The compounds were used as model compounds in an investigation which set out to derive a detailed understanding of the mechanisms Involved when metal ions are used to selectively modify the retention of compounds capable of interaction. This technique, which has parallels with ion-pair chromatography, provides another method by which the conditions of a separation may be altered and the selectivity adjusted to give better resolution. [Continues.] |
format | Default Thesis |
id | rr-article-9397430 |
institution | Loughborough University |
publishDate | 1988 |
record_format | Figshare |
spelling | rr-article-93974301988-01-01T00:00:00Z Retention-modification in HPLC using metal ions Simon J. Bale (7166390) Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified The effects of transition metal ions as components of the mobile phase on the retentions in HPLC of 2-aminophenol and selected α-diketones were studied on both ODS-silica and porous polymer columns. The compounds were used as model compounds in an investigation which set out to derive a detailed understanding of the mechanisms Involved when metal ions are used to selectively modify the retention of compounds capable of interaction. This technique, which has parallels with ion-pair chromatography, provides another method by which the conditions of a separation may be altered and the selectivity adjusted to give better resolution. [Continues.] 1988-01-01T00:00:00Z Text Thesis 2134/27578 https://figshare.com/articles/thesis/Retention-modification_in_HPLC_using_metal_ions/9397430 CC BY-NC-ND 2.5 |
spellingShingle | Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified Simon J. Bale Retention-modification in HPLC using metal ions |
title | Retention-modification in HPLC using metal ions |
title_full | Retention-modification in HPLC using metal ions |
title_fullStr | Retention-modification in HPLC using metal ions |
title_full_unstemmed | Retention-modification in HPLC using metal ions |
title_short | Retention-modification in HPLC using metal ions |
title_sort | retention-modification in hplc using metal ions |
topic | Other chemical sciences not elsewhere classified untagged Chemical Sciences not elsewhere classified |
url | https://hdl.handle.net/2134/27578 |